安装一个高密度聚乙烯升级的触发器
Tianhao Nan1,2, Quan Chen1,2, Zhangfan Zheng1,2
1State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.
通过乙烯/丁共聚化引入碳-碳双键使得可控的降解成为可能. 这创造了可用于上循环的有价值的寡合物,促进了可持续的聚烯开发.
科学领域:
- 聚合物化学
- 材料科学
- 可持续的化学
背景情况:
- 聚乙烯 (PE) 缺乏固有的降解点,阻碍了可持续的回收利用.
- 将CC债券引入PE提供了一个可控降解和上循环的策略.
- 现有的CC结合方法在控制共聚合物组成和规律性方面面临挑战.
研究的目的:
- 开发一种可控的方法,通过共聚化将CC键融入PE中.
- 调查由此产生的乙烯/丁 (E/BD) 共聚物的特性和降解行为.
- 为了证明分解产品的上循环潜力.
主要方法:
- 用于乙烯和丁 (E/BD) 共聚合的氨酸复合物.
- 描述了共聚物的特性,将其与商业高密度PE进行比较.
- 研究了共聚物的降解为α,ω-基聚合物.
- 通过原子转移激素聚合和不朽环开放聚合,证明了寡合物的上循环转化为兼容剂.
主要成果:
- 实现了可控的E/BD共聚化,并以均的1,4模式结合了布达.
- 由此产生的共聚物具有与商业高密度PE相匹配的物理,机械,加工和抗氧性能.
- 嵌入的CC键有助于控制降解为狭窄分布的α,ω-体寡合体.
- 成功地将这些寡合物转化为功能兼容剂.
结论:
- 胺复合物可用于控制PE功能化的E/BD共聚.
- 功能化PE保持了理想的性能,同时允许控制的降解.
- 这种方法提供了一个可行的途径,用于将聚烯可持续地转化为有价值的材料.
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