无形固体中的热激活间歇性流
Daniel James Korchinski1, Jörg Rottler1
1Department of Physics and Astronomy and Quantum Matter Institute, University of British Columbia, 2355 East Mall, Vancouver, BC V6T 1Z1, Canada. djkorchi@phas.ubc.ca.
Soft matter
|September 25, 2024
概括
这项研究揭示了无形固体在间歇流动条件下被破坏的标准态流动规律. 一个新的热激活应力尺度控制了这种模式中的流动行为,需要重新评估缓慢剪切效应.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 材料科学 材料科学 材料科学
- 类风病学 类风病学 类风病学
背景情况:
- 无形固体在剪切下表现出复杂的流动行为.
- 现有的风学模型通常假定连续流,这可能不适用于普遍.
研究的目的:
- 分析无形固体的平稳状态剪切形学,特别关注热激活过程.
- 为了确定在间歇性流动状态下,流体规律是如何变化的.
主要方法:
- 平均场理论的应用.
- 使用一个中等尺度弹性塑料模型.
- 在剪切下分析热激活的无形固体.
主要成果:
- 连续流量是由既定的规律 (例如,赫歇尔-布克利) 在高温和驾驶速度下描述的.
- 间歇性流,以状行为为特征,需要重新理解.
- 一个热激活应力尺度,x_a(T, γ̇),统一了温度和驱动速率对流量应力和事件大小的影响.
结论:
- 对于无形固体中间歇性流动来说,标准的气流学定律是不够的.
- 已识别的热激活应力尺度为该系统提供了通用描述符.
- 需要进一步研究玻璃过渡下缓慢切割的无形物质的气质学.
相关概念视频
Phase Transitions: Melting and Freezing
12.3K
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
12.3K
Viscosity
5.8K
When water is poured into a glass, it falls freely and quickly, whereas if honey or maple syrup is poured over a pancake, it flows slowly and sticks to the surface of the container. This difference in the flow of different kinds of liquids arises due to the fluid friction between the liquid layers and the liquid and the surrounding material. This property of fluids is called fluid viscosity. In this example, water has a lower viscosity than honey and maple syrup.
The SI unit of viscosity is...
The SI unit of viscosity is...
5.8K
Third Law of Thermodynamics
18.3K
A pure, perfectly crystalline solid possessing no kinetic energy (that is, at a temperature of absolute zero, 0 K) may be described by a single microstate, as its purity, perfect crystallinity,and complete lack of motion means there is but one possible location for each identical atom or molecule comprising the crystal (W = 1). According to the Boltzmann equation, the entropy of this system is zero.
18.3K
Polymer Classification: Crystallinity
2.8K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
2.8K
Heating and Cooling Curves
22.8K
When a substance—isolated from its environment—is subjected to heat changes, corresponding changes in temperature and phase of the substance is observed; this is graphically represented by heating and cooling curves.
For instance, the addition of heat raises the temperature of a solid; the amount of heat absorbed depends on the heat capacity of the solid (q = mcsolidΔT). According to thermochemistry, the relation between the amount of heat absorbed or released by a substance, q, and its...
For instance, the addition of heat raises the temperature of a solid; the amount of heat absorbed depends on the heat capacity of the solid (q = mcsolidΔT). According to thermochemistry, the relation between the amount of heat absorbed or released by a substance, q, and its...
22.8K
Phase Transitions
19.0K
Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to...
19.0K


