在丰富的阴极中对氧氧化的拓保护
Zhefeng Chen1, Wentao Zhang1, Shunning Li1
1School of Advanced Materials, Peking University, Shenzhen Graduate School, Shenzhen 518055, P. R. China.
The journal of physical chemistry letters
|September 26, 2024
概括
富含的分层氧化物具有高能量密度,但由于结构变化,其循环能力较差. 本次审查重点关注抑制这些正极材料中氧气释放的策略,以提高性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 富层氧化物 (LRLOs) 是下一代阴极材料的前景.
- 它们的高能量密度源于阳离子氧化还原活性.
- 提高可循环利用性需要抑制不可逆转的结构演变.
研究的目的:
- 为LRLOs释放氧气的材料设计策略提供视角.
- 为了突出LRLOs中氧氧还氧化物的化学成分.
- 讨论以拓为基础的减轻氧气迁移的策略.
主要方法:
- 对LRLOs现有文献的审查.
- 氧氧氧化化学的分析.
- 对氧释放物质拓效应的评估.
主要成果:
- 氧气释放是限制LRLO阴极循环能力的关键因素.
- 材料设计和拓影响氧气迁移.
- 现有策略可以缓解不可逆转的结构变化.
结论:
- 了解氧氧还氧化化学对于LRLO开发至关重要.
- 以拓为指导的材料设计可以提高阴极的可逆性.
- 洞察力可以导致高容量,稳定的LRLO阴极.
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