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Updated: Jun 11, 2025

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
10:57

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

Published on: April 10, 2018

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酸稳固的Cu集群预催化剂在CO2中实现了高能量和碳效率

Dongha Kim1, Sungjin Park1, Junwoo Lee2,3

  • 1The Edward S. Rogers Department of Electrical and Computer Engineering, University of Toronto, Toronto, Ontario M5S 1A4, Canada.

Journal of the American Chemical Society
|September 27, 2024
PubMed
概括

研究人员为酸性二氧化碳 (CO2) 电解开发了稳定的铜催化剂. 这些催化剂提高了C2+产品的能量效率和选择性,克服了酸性环境中的挑战.

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Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production08:40

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production

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Acid Halides to Ketones: Gilman Reagent01:14

Acid Halides to Ketones: Gilman Reagent

Lithium dialkyl cuprate, also known as Gilman reagents, selectively reduces acid halides to ketones. The acid chloride is treated with Gilman reagent at −78 °C in the presence of ether solution to produce a ketone in good yield.
As shown below, the mechanism proceeds in two steps. First, one of the alkyl groups of the reagent acts as a nucleophile and attacks the acyl carbon of the acid chloride to form a tetrahedral intermediate. This is followed by the reformation of the carbon–oxygen...
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