使用环保的欧原醇作为与三聚胺一起的稀释剂,用于水性氨酸的反应提取
Mohammed Saad1, Behnaz Asadzadeh2, Petri Uusi-Kyyny1
1Department of Chemical and Metallurgical Engineering, School of Chemical Engineering, Aalto University, P.O. Box 11000, Aalto, 00076, Finland.
Scientific reports
|September 27, 2024
概括
欧原醇和甲醇是有效的绿色溶剂,用于通过反应提取提取氨酸 (LA). 这项研究使用液体-液体平衡数据和热力学建模量化了它们的效率.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 绿色化学 绿色化学
背景情况:
- 酸 (LA) 是一种具有多种应用的关键平台化学物质.
- 有效的提取方法对于其工业可行性至关重要.
- 反应式提取提供了一个有前途的分离技术.
研究的目的:
- 为了研究从水溶液中反应提取氨酸 (LA) 的方法.
- 为了评估eugenol作为用于LA提取的绿色溶剂.
- 为了评估甲醇 (MeOH) 和三八胺 (TOA) 作为稀释剂的性能.
主要方法:
- 对三元和四元系统进行了液体-液体平衡 (LLE) 测量.
- 计算了LA的分布系数 (KD) 进行了计算.
- 使用非随机双液体 (NRTL) 过量的吉布斯能量模型进行相关联.
主要成果:
- 欧原醇在用TOA提取LA时表现出高的分布系数 (KD = 9.44) .
- 甲醇也被证明是用TOA提取LA的可行的稀释剂.
- 该NRTL模型成功地将实验阶段平衡数据关联起来.
结论:
- 尤根醇是一种适合和绿色溶剂,用于激活提取牛酸.
- 在这个过程中,甲醇可以有效地用作稀释剂.
- 热力学建模验证了提取性能.
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