新型切片陶SrBi2Nb2-2WSnO9:晶体结构,微观结构和介电性质
Sergei V Zubkov1, Ivan A Parinov2, Alexander V Nazarenko1,3
1Research Institute of Physics, Southern Federal University, Rostov-on-Don 344090, Russia.
Materials (Basel, Switzerland)
|September 28, 2024
概括
研究人员通过用锡和替代来合成一种新陶,SrBi2Nb2-2xWxSnxO9. 用锡和进行兴奋剂改善了电物理性能,减少了损失,并增加了这种奥里维利乌斯-斯莫伦斯基相位材料的导电性.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 陶工程 陶工程 陶工程
背景情况:
- 奥里维利乌斯-斯莫伦斯基相 (ASP) 以其独特的结构和电气特性而闻名.
- 二 bismuth niobate (SrBi2Nb2O9) 是该类的关键材料,但其性能可以进一步优化.
- 之前的研究表明,在这种材料中使用锡 (Sn) 作为剂存在局限性.
研究的目的:
- 为了合成和表征一种新的压陶化合物,SrBi2Nb2-2xWxSnxO9.
- 研究与锡 (Sn) 和 (W) 联合剂对SrBi2Nb2O9.9的结构和电物理性能的影响.
- 挑战现有的关于锡作为这些材料中兴奋剂元素的无效性的概念.
主要方法:
- 合成的高温固体相反应.
- 用X射线衍射 (XRD) 进行结构分析和相位识别.
- 介电光谱测量相对电容度 (ε/ε0) 和介电损失触点 (tan δ) 在各种频率和温度下.
主要成果:
- 成功合成了单相和双相SrBi2Nb2-2xWxSnxO9 (x = 0.10.4) 与奥里维利乌斯-斯莫伦斯基相结构 (空间组A21am).
- 观察到SrBi2Nb2-2xWxSnxO9 (x = 0.1) 的电物理特性显著改善,特别是介电损失减少和相对电容度增加.
- 首次证明锡 (Sn) 可以有效地增强SrBi2Nb2O9的电物理特性,反驳了之前的假设.
结论:
- 将SrBi2Nb2O9与锡和联合合,可以获得具有增强电物理特性的新型压陶.
- 化合物SrBi2Nb2-2xWxSnxO9 (x = 0.1) 由于减少损耗和增加电容性,对介电应用具有有前途的性能.
- 锡被证实是提高SrBi2Nb2O9基材料性能的一种可行和有益的辅助剂.
关键词:
奥里维利乌斯-斯莫伦斯基阶段克里度温度 TC 克里度温度 TCSrBi2Nb2-2xWxSnxO9 (x=0.1,0.2,0.3,0.4) 的结果是没有一个.激活能量 Ea Ea Ea Ea Ea Ea Ea Ea Ea Ea Ea Ea Ea Ea相对允许度 ε/ε0更多相关视频
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