微观结构通过核化微粒状状铁素的精细化,通过含有Ti的核心外结构颗粒刺激低碳钢中的核状铁素
Zhu Yan1, Chao Wang1, Hua Duan1
1The State Key Laboratory of Rolling and Automation (RAL), Northeastern University, Shenyang 110819, China.
Materials (Basel, Switzerland)
|September 28, 2024
概括
脱氧化钢具有显著增强的冲击性,这是由于状铁 (AF) 的形成. 核心外Ti2O3/TiO颗粒和低格子无注册促进AF核化,改善钢材性能.
科学领域:
- 材料科学 材料科学 材料科学
- 金工业是金工业的一个方面.
- 物理化学 物理化学
背景情况:
- 状铁 (AF) 的形成对于提高钢的性至关重要.
- 使用 (Mn) 和 (Al) 的传统脱氧方法在冲击性方面取得了有限的改善.
- 了解核化机制是开发先进高强度钢的关键.
研究的目的:
- 为了研究热Ti脱氧化钢中无铁酸盐 (AF) 的微观结构,机械性能和核化机制.
- 阐明特定脱氧产品在促进AF形成中的作用.
- 为了将微观结构与增强的冲击性相关联.
主要方法:
- 热Ti脱氧化钢的实验研究.
- 微结构分析以识别AF和第二阶段粒子.
- 机械性能测试,特别是在低温下冲击性.
- 核化机制的分析,包括格子无注册和定向关系.
主要成果:
- 与Mn (9 J) 和Al (18 J) 脱氧化钢相比,Ti脱氧化钢的冲击性显著增加 (在-20 °C下为144 J).
- 互锁的状铁被确定为Ti脱氧化钢中占主导地位的微结构.
- 核心外结构的Ti2O3/TiO粒子被发现是AF的有效核化剂.
- 确定了TiO和AF之间的低晶格失序,以及与MnS相邻的Mn-depleted zone (MDZ) 的形成,是促进AF核化的关键因素.
结论:
- 脱氧化有效地促进了无环铁的形成,从而使钢具有优越的冲击性.
- 核心外Ti2O3 / TiO粒子由于有利的晶体学匹配,作为AF的关键核化地点.
- Ti2O3 / TiO颗粒,MnS和由此产生的Mn-depleted区域之间的相互作用为增强AF核和提高钢铁性能提供了一个全面的机制.
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