生物环氧树脂基于利格宁和酸作为木材粘合剂-特征和结合性质
Ivana Gavrilović-Grmuša1, Milica Rančić1, Tamara Tešić1
1Faculty of Forestry, University of Belgrade, 11030 Belgrade, Serbia.
Polymers
|September 28, 2024
概括
这项研究引入了环保木材生物粘合剂,使用木质素和酸作为有毒硬化剂的替代品. 这些生物环氧粘合剂具有高抗拉力剪切强度,为木材粘合应用提供了可持续的替代方案.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 绿色化学 绿色化学
背景情况:
- 传统的木材粘合剂通常依赖于有毒的,不环保的氨基基基硬化剂.
- 酸和酸是天然的多,富含活性基团.
- 迪格利基乙烯双A (DGEBA) 是一种常见的,但与环境有关的环氧树脂成分.
研究的目的:
- 开发和设计用于木材粘合剂应用的生物氧化物,由素和酸制成.
- 调查使用素/氧化素素和酸作为商业硬化剂和DGEBA的替代品.
- 评估这些新型生物环氧粘合剂的交叉连接和性能.
主要方法:
- 红素的氧化,以产生环氧红素.
- 素/环氧素和酸与商业环氧树脂的反应.
- 里埃变换红外光谱 (FTIR) 用于研究交叉链接.
- 拉伸切割强度测试用于评估粘合剂性能.
主要成果:
- 酸和酸有效地取代了环氧树脂中的氨酸硬化剂.
- 环氧化红素作为DGEBA的可行的替代品.
- 生物环氧粘合剂表现出显著的拉力剪切强度 (5.8410.87 MPa).
- 所有测试的样本显示木材中100%的骨折,表明粘合力强.
结论:
- 酸和酸可以用来制造有效的生物环氧木材粘合剂.
- 开发的生物粘合剂为传统木材粘合剂提供了高性能,环保的替代品.
- 这项研究为粘合剂技术中可持续材料提供了一种新的方法.
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