PFDTS/TiO2涂层对基石微观结构和湿行为的影响
Yuanxia Li1, Fangfang Zeng1, Guang Yang1
1School of Materials and Metallurgy, Guizhou University, Jiaxiu South Road, Huaxi District, Guiyang 550025, China.
ACS omega
|September 30, 2024
概括
研究人员通过涂上二氧化纳米颗粒和化合物来增强化 (PG) 的疏水性. 这提高了其作为可持续建筑材料的潜力,减少了浪费,并带来了经济效益.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 石膏 (PG) 是湿处理酸生产的主要副产品,这给废物管理带来了重大挑战.
- 由于其不良的疏水性,目前对PG的利用是有限的,这阻碍了其作为传统水泥材料的替代品的使用.
- 提高PG的疏水性质可以释放其大规模应用的潜力,提供经济和环境优势.
研究的目的:
- 在α-半酸基石膏 (α-HPG) 上合成和应用疏水性表面涂层.
- 为了研究表面疏水性修饰的机制.
- 评估改性PG作为可持续建筑材料的潜力.
主要方法:
- 使用性溶液化α-HPG以产生OH-α-HPG.
- 将二氧化纳米颗粒 (TiO2) 与 perfluorodecyltriethoxysilane (PFDTS) 混合在化表面上.
- 使用水接触角测量,FTIR,XPS和SEM进行表征,以评估疏水性质和表面化学.
主要成果:
- 表面修改显著增加了疏水性,OH-α-HPG-PT的接触角度为146.7°.
- 经过修改的涂层表现出了出色的化学稳定性和耐久性,在严格的浸泡和粘附测试后保持高的接触角度.
- 水氧化增强了PFDTS和TiO2在PG表面上的化学吸收,形成了一个强大的疏水层.
结论:
- 开发的sol-gel和浸方法有效地增强了phosphogypsum的疏水特性.
- 改性石与其他材料具有卓越的兼容性,表明其在建筑中使用的潜力.
- 这项研究为全面利用石废物提供了一个有前途的途径,为可持续发展做出贡献.
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