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用芳香化合物合的焦糖作为羊毛织物无素和的阻燃策略
Sheng-Nan Ma1, Jin-Ping Guan1, Xian-Wei Cheng1
1Key Laboratory of Flame Retardancy Finishing of Textile Materials (CNTAC), College of Textile and Clothing Engineering, Soochow University, 199 Ren'ai Road, Suzhou 215123, China.
International journal of biological macromolecules
|September 30, 2024
概括
研究人员开发了一种新型的,环保的阻燃剂,由焦糖和芳香化合物用于羊毛织物. 这种生物基处理提高了消防安全,而不会影响织物质量或洗后的耐用性.
科学领域:
- 材料科学 材料科学 材料科学
- 织工程 织工程 织工程
- 聚合物化学 聚合物化学
背景情况:
- 织行业需要可持续的,不含素和的阻燃剂.
- 羊毛织物被广泛使用,但为了安全需要增强的阻燃性.
研究的目的:
- 为羊毛织物开发和评估一种新的生物基阻燃剂.
- 为了研究修改织物的阻燃性,耐用性和机制.
主要方法:
- 使用葡萄糖和p-phthaldialdehyde通过焦糖化和阿尔多尔反应合成一种改性焦糖 (Car@PDA).
- 将Car@PDA应用于羊毛织物,并评估阻燃性 (LOI,损坏的长度),洗耐用性和热性能.
- 对阻燃机制的分析,包括纤维阻燃相互作用和焦炭形成.
主要成果:
- 经过修改的羊毛织物表现出明显改善的阻燃性,氧气限制指数 (LOI) 为32.5%,损伤长度减少 (10.1厘米).
- 由于希夫基和静电相互作用,Car@PDA处理证明了出色的洗耐用性,在10个循环后达到B1阻燃标准.
- 观察到热释放能力降低和火灾增长率降低,这表明火灾安全性提高,对羊毛的抗拉强度和手柄的影响最小.
结论:
- 一种可持续的,生物基的,无和的阻燃剂 (Car@PDA) 已成功开发用于羊毛织物.
- 汽车@PDA修改提供了卓越的阻燃性和耐久性,为更安全的蛋白质基础织品提供了有前途的解决方案.
- 该研究强调了一种创新的方法,用于为织工业创造高性能,环保的阻燃剂.
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