红土临界区的循环受到同位素的限制
Xiaoqing He1, Wenhan Cheng2, Ziyao Fang3
1State Key Laboratory of Lithospheric and Environmental Coevolution, University of Science and Technology of China, Hefei 230026, China; School of Carbon Neutrality Science and Engineering, Anhui University of Science and Technology, Hefei 231131, China; CAS Center for Excellence in Comparative Planetology, Hefei 230026, China.
The Science of the total environment
|October 2, 2024
概括
在土中的 (Cr) 同位素分离受有机物和氧化还原变化的影响. 种植会影响Cr循环,使长期耕种的土壤成为 (VI) 污染物的潜在沉池.
科学领域:
- 环境地质化学环境地质化学
- 土壤科学 土壤科学
- 同位素地球化学 同位素地球化学
背景情况:
- (Cr) 同位素系统对于跟踪污染和氧化还原变化至关重要.
- 在土壤中,Cr的转化机制和同位素分离仍然不太清楚.
研究的目的:
- 在中国南方两片红土田中研究Cr同位素成分 (δ53Cr).
- 阐明在耕种土壤中的Cr转化机制和同位素分离过程.
主要方法:
- 在年轻和老的田土壤概况中分析Cr同位素组成 (δ53Cr).
- 三步水实验,以确定土壤部分 (Fe-Mn氧化物,有机物质) 中的Cr分区和同位素特征.
主要成果:
- δ53Cr值在 -0.34‰至 -0.06‰之间,而较旧的字段显示了更多的正值.
- 铁和氧化物富含重Cr同位素,而有机物则显示较轻的特征,表明Cr (VI) 减少.
- 种植显著改变了Cr循环,田作为潜在的Cr (VI) 沉.
结论:
- 在气候变化期间的Cr同位素分离是复杂的,涉及有机物对Cr的逆降解.
- 在田长期种植会增加Cr (VI) 的保留和易受污染的可能性.
- 氧化还原过程和有机物相互作用是土壤中Cr同位素分化的关键驱动因素.
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