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Updated: Jun 23, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

电子结构决定了几何结构:键的长度在循环中交替[2n]碳

Xi Chen1,2,3, Xueyuan Yan1, Zihan Liu3

  • 1College of Chemistry & Chemical and Environmental Engineering, Weifang University, Weifang, Shandong 261061, China.

The journal of physical chemistry. A
|October 3, 2024
PubMed
概括

电子相关性,而不是几何学,导致循环[2n]碳中的双反芳香性. 密度函数理论 (DFT) 对较大的循环碳化合物是可靠的,但对较小的碳化合物 (如C6) 需要谨慎.

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