相关实验视频
Updated: Jun 11, 2025

09:04
Fabrication of VB2/Air Cells for Electrochemical Testing
Published on: August 5, 2013
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高能量密度全V2O5电池
Guolong Wang1, Jingqi Wang1, Jiale Song1
1State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, No. 28, Xianning West Road, Xi'an, Shaanxi, 710049, P. R. China.
Small (Weinheim an der Bergstrasse, Germany)
|October 4, 2024
概括
这项研究引入了一种高压氧化物 (V2O5) 对称电池. 这种新的设计实现了高能量密度和稳定性,性能优于当前的,和基对称电池.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 对称电池提供了成本效益和安全性,但由于能量密度低而受到限制.
- 由于双极电极选择有限,将高特定容量与高电压相结合是具有挑战性的.
研究的目的:
- 构想一个具有明确电压平原的全氧化 (V2O5) 高压对称电池.
- 使用V2O5间隔化学解离阴极和阳极氧化还原反应.
主要方法:
- 一个分层的V2O5-碳复合材料 (VO-C) 双极电极的制造.
- 展示VO-C作为一个高性能阴极和阳极在对称的全电池配置.
主要成果:
- 对称的全电池实现了174mAhg-1的高容量,在0.5C时达到2.9V以上的峰值电压.
- 从0.5C到10C保持81%的显著容量保留,在5C300个循环后保持70%.
- 能量密度达到429Wh kg-1,超过现有的基于Li/Na/K的对称电池.
结论:
- 开发的基于V2O5的对称电池显著提高了性能.
- 这项工作为未来的高性能电池技术提供了新的设计策略.
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