和锡的甲基化由河口微生物地毯
Richard F Lee1, K Kannan2, H Windom1
1Skidaway Institute of Oceanography, University of Georgia, 10 Ocean Science Circle, Savannah, GA 31411, USA.
Marine pollution bulletin
|October 4, 2024
概括
微生物中的硫酸盐降解细菌甲基化锡和. 这一过程对于将甲基和甲基引入海洋食物网至关重要,影响河口生态系统.
科学领域:
- 环境微生物学环境微生物学
- 生物地质化学生物地质化学
- 生态毒理学 生态毒理学
背景情况:
- 河口环境中的微生物地毯是各种微生物群落的宿主.
- 和锡等金属的甲基化可以增加它们的生物可用性和毒性.
- 了解负责金属甲基化的微生物过程对于评估生态风险至关重要.
研究的目的:
- 确定在河口微生物中形成甲基和甲基的微生物代理.
- 为了研究易受甲基化作用的的化学形式.
- 评估微生物在甲基化金属进入海洋食物网中的作用.
主要方法:
- 在受控条件下,将锡和盐添加到河口微生物上.
- 用抑制剂 (酸盐) 和兴奋剂 (酸盐) 进行化实验,以探测代谢途径.
- 随着时间的推移,对甲基和甲基的形成进行分析.
- 测试不同化合物的甲基化 (化,囊素,硫化).
主要成果:
- 在添加母金属盐后,在微生物地毯中观察到大量的甲基和甲基的形成.
- 甲基化被酸盐抑制,被酸盐刺激,表明硫酸盐减少细菌的参与.
- 无菌地毯没有产生甲基化金属,证实了微生物活动.
- 甲基是由化和囊蛋白形成的,但不是从硫化形成的.
结论:
- 河口微生物地毯中的减少硫酸盐的细菌负责锡和的甲基化.
- 无氧沉积物中与有机复合物结合的可能由这些微生物群体甲基化.
- 微生物甲基化是甲基和甲基进入河口和海洋食物网的重要途径.
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