重复反应纤维素基水凝的可逆光/光色切换用于信息加密
Yu Zhong1, Zhiqi Wang1, Lingqi Quan1
1State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures, School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China.
Journal of colloid and interface science
|October 4, 2024
概括
新的基于纤维素的水凝为防伪应用提供稳定,可逆的光和光色切换. 这些先进的材料可以实现安全的信息加密和解密,并提高耐用性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 纳米技术 纳米技术
背景情况:
- 开发稳定,可重复的可逆切换水凝对于先进的防伪技术至关重要.
- 现有的水凝在稳定性和机械性能方面面临挑战,这限制了它们的实际应用.
研究的目的:
- 为了合成强大的,基于纤维素的智能响应性水凝,具有可逆光和光色切换能力.
- 为了提高水凝的稳定性,机械强度和切换性能,用于信息加密.
主要方法:
- 在水热过程中自由基移植共聚化,以制造化学交联的纤维素基水凝.
- 在水凝矩阵中加入光色氨基酸盐和光碳点.
- 机械性能,可逆切换行为和信息加密/解密能力的表征.
主要成果:
- 实现了高拉伸强度 (280 kPa) 和压力强度 (560 kPa),明显超过报告值.
- 已证明可逆光/光色切换 (黄色到绿色) 和图案打印/擦除.
- 缩短光色自色时间到60°C的25分钟,并开发了一种使用乙醇的光恢复方法.
结论:
- 成功开发出环保,稳定的基于纤维素的水凝,具有双重可逆切换特性.
- 合成的水凝适用于先进的防伪和信息加密应用.
- 这一战略为创造具有增强性能的智能响应材料提供了一个有前途的途径.
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