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具有双活性中心的基于Ag-Ru的高缩电催化剂用于高度稳定的超低温空气电池
Ziming Qiu1, Xiaotian Guo1, Shuai Cao1
1School of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, Jiangsu, P. R. China.
Angewandte Chemie (International ed. in English)
|October 6, 2024
概括
这项研究引入了可充电空气电池的新型高合金催化剂,在氧气反应和超低温能量储存中表现出卓越的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 先进的双功能催化剂对于可充电的空气电池 (ZAB) 是至关重要的.
- 有效的氧演变反应 (OER) 和氧减少反应 (ORR) 催化剂是ZAB性能所需的.
研究的目的:
- 开发一种高效的OER和ORR双功能催化剂,使用双活性中心合金化策略.
- 为了利用高效应用于催化剂结构和性能调节.
主要方法:
- 通过MOF辅助热解替代合金制造一个CoCuFeAgRu高合金 (HEA) 催化剂.
- 将HEA催化剂固定在多孔的化碳纳米片中.
- 对ORR和OER的催化性能的表征,以及灵活的可充电ZAB的组装.
主要成果:
- HEA催化剂对ORR和OER都表现出极好的双功能催化活性.
- 达到136.53mW/cm2的峰值功率密度和987.9mAh/gZn的能量密度.
- 组装后的ZAB在-40°C (601.6 mAh/gZn能量密度) 和1650小时的循环稳定性下表现出显著的性能.
结论:
- HEA催化剂的卓越性能源于Ag和Ru双活性中心的协同效应以及合金诱导的电子结构优化.
- 开发的催化剂显示了高性能,低温可充电ZAB的巨大潜力.
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