Jove
Visualize
联系我们
JoVE
x logofacebook logolinkedin logoyoutube logo
关于 JoVE
概览领导团队博客JoVE 帮助中心
作者
出版流程编辑委员会范围与政策同行评审常见问题投稿
图书馆员
用户评价订阅访问资源图书馆顾问委员会常见问题
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experiments存档
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教师资源中心教师网站
使用条款与条件
隐私政策
政策

相关概念视频

Bonding in Metals02:32

Bonding in Metals

46.9K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
46.9K
Complexation Equilibria: Factors Influencing Stability of Complexes01:09

Complexation Equilibria: Factors Influencing Stability of Complexes

347
In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
347
Metallic Solids02:37

Metallic Solids

18.3K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
18.3K
Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

Crystal Field Theory - Tetrahedral and Square Planar Complexes

41.7K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
41.7K
Atomic Nuclei: Nuclear Relaxation Processes01:23

Atomic Nuclei: Nuclear Relaxation Processes

632
In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin to precess and orient themselves along (lower energy) or against (higher energy) the direction of the field. At equilibrium, a slight excess population of spins exists in the lower energy state. Because the direction of the magnetic field is fixed as the z-axis,  the precessing magnetic moments are randomly oriented around the z-axis.
632
Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

26.2K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
26.2K

您也可能阅读

相关文章

通过共同作者、期刊和引用图与本文相关的文章。

排序
Same author

Lateral graphene-metallene interfaces at the nanoscale.

Nanoscale·2025
Same author

Simulating iron in oxygen-containing environments: An improved Fe-O interaction for density-functional tight-binding.

The Journal of chemical physics·2025
Same author

The structural behavior of physisorbed metallenes.

Nanoscale advances·2025
Same author

Stability limits of elemental 2D metals in graphene pores.

Nanoscale·2019
Same author

Primetime learning: collaborative and technology-enhanced studying with genuine teacher presence.

International journal of STEM education·2019
Same author

Optically Forged Diffraction-Unlimited Ripples in Graphene.

The journal of physical chemistry letters·2018

相关实验视频

Updated: Jun 11, 2025

Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope
09:06

Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope

Published on: March 24, 2019

8.1K

温和的张力稳定了原子细的金属.

Kameyab Raza Abidi1, Pekka Koskinen1

  • 1Nanoscience Center, Department of Physics, University of Jyväskylä, 40014 Jyväskylä, Finland. pekka.j.koskinen@jyu.fi.

Nanoscale
|October 7, 2024
PubMed
概括

这项研究表明,晶体金属 (2D材料) 在拉力应变和低原子密度下最稳定,挑战了先前的合成结构假设. 这一发现为创建稳定的二维金属材料提供了新的策略.

科学领域:

  • 材料科学 材料科学 材料科学
  • 凝聚物质物理学 凝聚物质物理学
  • 纳米技术纳米技术

背景情况:

  • 金属是原子薄的2D材料,没有散装层结构.
  • 稳定金属是具有挑战性的,因为同位素金属结合,阻碍了与理论预测的直接比较.

研究的目的:

  • 探索45种金属在六种格子类型和不同密度的能量和动态稳定性.
  • 为理解和稳定晶体金属提出一个新的范式.

主要方法:

  • 使用密度函数理论 (DFT) 的计算.
  • 在六个晶格 (蜂形,方形,六角形和形变体) 中研究了45种金属.
  • 分析了不同原子密度和拉伸应变下的稳定性.

主要成果:

  • 在270个配置中确定了128个动态稳定的晶格,主要在拉伸应变下和零星密度下.
  • 发现能量最小值往往导致动态不稳定性,无形化和平面性丧失.
  • 提出晶体金属是产生膜的,而不是固定的结构.

结论:

  • 晶体金属在拉伸应变和低原子密度下表现出增强的稳定性.

更多相关视频

Determining the Mechanical Strength of Ultra-Fine-Grained Metals
05:04

Determining the Mechanical Strength of Ultra-Fine-Grained Metals

Published on: November 22, 2021

2.2K
Applying Dynamic Strain on Thin Oxide Films Immobilized on a Pseudoelastic Nickel-Titanium Alloy
09:35

Applying Dynamic Strain on Thin Oxide Films Immobilized on a Pseudoelastic Nickel-Titanium Alloy

Published on: July 28, 2020

4.9K

相关实验视频

Last Updated: Jun 11, 2025

Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope
09:06

Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope

Published on: March 24, 2019

8.1K
Determining the Mechanical Strength of Ultra-Fine-Grained Metals
05:04

Determining the Mechanical Strength of Ultra-Fine-Grained Metals

Published on: November 22, 2021

2.2K
Applying Dynamic Strain on Thin Oxide Films Immobilized on a Pseudoelastic Nickel-Titanium Alloy
09:35

Applying Dynamic Strain on Thin Oxide Films Immobilized on a Pseudoelastic Nickel-Titanium Alloy

Published on: July 28, 2020

4.9K
  • 提出了一个新的范式,将金属视为产生膜.
  • 这种方法可以指导合成更大,更稳定的金属样本用于等离子体,光学和催化学的应用.