早期水化过程对水静压变化的影响 在不同温度下,水泥糊的水静压变化
Youzhi Zheng1,2, Jun Zhao1,2, Shiguo Tang1,2
1Engineering Technology Research Istitute, Petrochina Southwest Oil and Gas Field Companly, Chengdu 610017, China.
ACS omega
|October 7, 2024
概括
在水泥糊中,液压压力迅速下降,导致气体流通. 这项研究将压力变化与水泥水化和微观结构的发展联系起来,提出了基于水化反应的预测方法.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 石油工程是石油工程中的一个.
背景情况:
- 混凝土糊中的液压压力迅速下降是混凝土加工过程中早期气体流通的主要原因.
- 了解水泥液压压力,温度和水分之间的关系对于防止道化至关重要.
研究的目的:
- 为了研究不同温度 (30°C-180°C) 的水静压在水泥的变化.
- 阐明早期水合,微观结构的发展和水静压变化之间的关系.
- 提出一种方法来预测液压的快速下降.
主要方法:
- 在各种温度下测量水电压的水泥糊.
- 使用X射线粉末衍射 (XRD),热重力测量 (TGA) 和扫描电子显微镜 (SEM) 分析微观结构和水合.
主要成果:
- 水静压曲线显示稳定,然后在较低的温度 (30-90°C) 迅速下降.
- 在高温 (150°C) 时,压力最初会增加,稳定,然后迅速下降.
- 微观结构从粒子水化产品演变为"凝框架",隔离自由水并导致压力降低.
结论:
- 液压压力快速下降的时间与温度相关,并符合博尔兹曼函数.
- 水泥的水化和微观结构的演变,特别是凝框架的形成,直接影响水静压的行为.
- 开发了一种基于水化反应动力学的液态压力下降的预测方法.
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