通过吸附性预化增强炉柴油的超深水解硫
Narjes Ghaloum1, Muhieddine A Safa1, Hamza Albazzaz1
1Petroleum Research Center, Kuwait Institute for Scientific Research, P.O. Box 24885, Safat 13109, Kuwait.
ACS omega
|October 7, 2024
概括
吸附性脱 (ADN) 与水解硫 (HDS) 结合,可以有效地从高燃料中产生超低硫柴油 (ULSD). 这种协同方法降低了生产成本,提高了燃料质量.
科学领域:
- 石油精炼 石油精炼 石油精炼
- 催化剂是一种催化剂.
- 环境工程 环境工程
背景情况:
- 生产超低硫柴油 (ULSD) 面临的挑战是由于化合物抑制水解硫 (HDS).
- 现有的方法在深度HDS的能源效率和成本效益方面扎.
研究的目的:
- 为了研究吸附性脱 (ADN) 和HDS对焦油 (CD) 的超深HDS的协同效应.
- 评估预脱对HDS效率,能源消耗,催化剂寿命和产品质量的影响.
主要方法:
- 将碳基吸附剂DNA与传统的HDS工艺相结合.
- 进行试点规模的研究,以验证ULSD生产的综合DNA-HDS方法.
主要成果:
- 预化显著提高了HDS的反应性,使所需的温度降低了20°C.
- 综合工艺降低了能源和的消耗,延长了催化剂的寿命,提高了产品质量 (低芳,密度;更高的 cetane 指数,稳定性).
- 为了预测性能,在日志 (产品硫度) 和HDS温度之间建立了线性关系.
结论:
- 结合的ADN-HDS工艺提供了一条节能和成本效益的途径,从具有挑战性的原料,如CD.
- 预化是提高HDS性能和产品特性的一个关键步骤.
- 这些发现为通过HDS温度控制优化ULSD生产提供了一个预测模型.
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