酸盐离子对d-glucosone的作用:催化转化为aldonates,涉及C1-C2转化

Wenhui Zhang1,2, Anthony S Serianni1

  • 1Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556-5670, United States.

ACS omega
|October 7, 2024
PubMed
概括

对d-[1-13C]葡萄 (1) 的基酸盐处理通过C1-C2转换产生d-[2-13C]葡萄酸盐 (2) 和d-[2-13C]酸盐 (3). 这种不可逆转的反应涉及不同的双基复合物,并产生像d-[1-13C]阿拉比诺斯 (4) 这样的副产品.

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