来自不同级别的煤炭的基于煤炭的石墨烯:在离子电池中,特殊的储能性能
Lanhao Wang1,2, Xiaodong Yu1,2, Zhendong Jiang3,4
1State Key Laboratory of Coking Coal Resources Green Exploitation, China University of Mining and Technology Xuzhou 221116 China.
RSC advances
|October 7, 2024
概括
来自煤炭的减少石墨烯氧化物 (CrGO) 显示出作为离子电池 (SIB) 的阳极材料的前景. 这种CrGO提供了高容量和稳定性,推进了SIB技术并使可持续的煤炭利用成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电池 (SIB) 需要先进的阳极材料来提高性能.
- 煤炭是一种易于获得的碳前体,用于储能应用.
研究的目的:
- 合成和评估以煤为基础的减少氧化石墨烯 (CrGO) 作为SIBs的阳极材料.
- 为了研究煤炭等级对CrGO用于储存的特性的影响.
主要方法:
- 修改后的哈默斯方法和高温热还原被用于从煤基石墨 (CG) 制备CrGO.
- 在SIB中测试了CrGO的电化学性能,包括容量,速率能力和循环稳定性.
主要成果:
- 来自高级煤的CrGO表现出增强的石墨化和脱皮.
- 在0.03Ag-1时,CrGO显示出331mAhg-1的高初始可逆容量.
- 实现了卓越的速率能力 (75mA hg-1在10A g-1) 和循环稳定性 (123mA hg-1在1000个循环后,91.8%的保留率).
结论:
- 来自煤炭的CrGO是SIBs的一种可行的高性能阳极材料.
- 这项研究促进了煤炭资源在能源储存中的绿色和高价值利用.
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