球磨机对聚乙烯四甲酸盐微结构的影响
1Department of Chemistry, McGill University, Montréal, QC, H3A 0B8, Canada.
ChemSusChem
|October 7, 2024
概括
用于回收的球磨聚乙烯二甲 (PET) 迅速改变了它的微观结构. 削建立了一个一致的~30%的结晶度,为塑料回收研究提供了一个有价值的参考.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 聚乙烯二甲 (PET) 是一种广泛使用的聚合物,有助于塑料废物.
- 对于环境可持续性而言,PET回收技术至关重要.
- 球磨是塑料微化的一个关键技术,并且在酶性水解中表现有前途.
研究的目的:
- 系统地研究各种球磨条件引起的PET微观结构变化.
- 描述磨削频率和持续时间对PET的影响.
- 建立PET削和回收的参考指南.
主要方法:
- 研究了各种形式的PET,包括消费前和后的材料和织品.
- 应用了一系列的球磨频率和持续时间.
- 分析了粒子大小,晶度 (使用差分扫描热度计和粉末X射线衍射) 和形态 (使用扫描电子显微镜).
主要成果:
- 球磨导致PET晶度在15分钟内以30Hz的频率接近30%左右.
- 研磨条件影响了颗粒大小,结晶性和表面形态.
- 在球磨加工过程中观察到无形和晶体区域之间的平衡.
结论:
- 球磨削显著改变PET微观结构,建立一个一致的水晶度水平.
- 这些发现为优化回收中的PET削工艺提供了必要的数据.
- 这项研究作为未来关于PET回收和材料转换的研究的基础参考.
相关概念视频
Types of Step-Growth Polymers: Polyesters
2.2K
The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
2.2K
Polymer Classification: Architecture
2.7K
Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
2.7K
Polymer Classification: Crystallinity
2.8K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
2.8K
Free-Radical Chain Reaction and Polymerization of Alkenes
7.7K
The conversion of alkenes to macromolecules called polymers is a reaction of high commercial importance. The structure of the polymer is defined by a repeating unit, while the terminal groups are considered insignificant. The average degree of polymerization represents the number of repeating units in the polymer molecule and is denoted by the subscript n.
7.7K


