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使用静电悬浮测量二元合金液体的过量体积:磁体体积对正过量体积的影响
Lei Wang1, Yong Chan Cho1, Yun-Hee Lee1
1Frontier of Extreme Physics, Space Metrology Group, Korea Research Institute of Standards and Science, 209 Gajeong-Ro, Yuseong-Gu, Daejeon 34113, Republic of Korea.
The Journal of chemical physics
|October 8, 2024
概括
合金二元融会影响过剩体积 (VE) 和液体稳定性. 磁性和热力学因素有助于VE,影响合金属性.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 热力学是一种热力学.
背景情况:
- 了解合金融特性对于材料开发至关重要.
- 过量体积 (VE) 是一个关键参数,反映了合金中的原子相互作用.
研究的目的:
- 为了研究二元可混合和复合合金化的过量体积 (VE).
- 探索混合热量 (ΔHmix),磁性特性和 VE.之间的关系.
- 分析合金对液体稳定性的影响.
主要方法:
- 利用静电悬浮来研究24种二元合金化的情况.
- 进行特定热量测量以观察磁效应.
- 分析了合金元素中VE,ΔHmix和电子计数之间的相关性.
主要成果:
- 具有接近零 ΔHmix 的 Pd50X50 和 Pt50Fe50 固体溶液显示出正 VE 和增强液体稳定性.
- 化合物合金液体具有负 ΔHmix 呈现负 VE.
- 观察到磁体体积效应,随着X中电子数量的增加,Pd50X50和Pt50X50.的电子数量随着VE的减少而增加.
结论:
- 合金融中的过量体积形成是由热力学和磁性贡献的组合控制的.
- 合金可以显著改变液体的稳定性和体积,受电子相互作用和磁现象的影响.
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