在原子接口上调节单个原子的局部协调圈,以实现高效的氧气进化反应
Ashwani Kumar1, Marcos Gil-Sepulcre2, Jean Pascal Fandré1
1Max Planck Institut für Kohlenforschung, 45470 Mülheim an der Ruhr, Germany.
Journal of the American Chemical Society
|October 8, 2024
概括
我们通过将原子嵌入到NiO表面来增强氧进化反应 (OER) 的单原子催化剂. 这提高了清洁能源技术的耐用性和活力.
科学领域:
- 催化剂
- 材料科学
- 电化学
背景情况:
- 单原子催化剂 (SAC) 对于高效的氧化演化反应 (OER) 催化是至关重要的.
- 在恶劣的开放式环境条件下,SAC的耐用性问题限制了其实际应用.
- 较弱的金属支相互作用和金属溶解损害了SAC的性能.
研究的目的:
- 提高氧化演化反应 (OER) 的单原子催化剂的性能和耐用性.
- 在氧化 (NiO) 表面系统调节单原子 (Ir SAC) 的局部协调.
- 调查定制原子协调对OER活动和稳定的影响.
主要方法:
- 在NiO表面的Ir SACs的原子级调节.
- 用于分析金属支相互作用的X射线吸收光谱 (XAS).
- 操作X射线吸收和拉曼光谱以进行现场表征.
- 用于评估催化性能的pH依赖性活性测试.
主要成果:
- 嵌入的Ir单原子 (Iremb-NiO) 显示了Ir-Ni第二层相互作用的2倍增加,表明更强的金属支键.
- 与商业的IrO和传统的Ir SAC相比,Iremb-NiO具有更高的性OER质量活性和长期耐用性 (1 mV/h降解).
- 在Operando研究中发现了NiOOH的高价值原子Ir位点,利用氧机制,绕过传统的缩放关系.
- 增强的Ir-Ni相互作用赋予了结构刚性,缓解了Ir溶解,并确保了持续的OER动力学.
结论:
- 通过将它们嵌入到NiO中来定制Ir SAC的协调范围,大大提高了OER的性能和持久性.
- 更强的金属支相互作用是防止金属溶解和保持催化剂稳定性的关键.
- 嵌入式Ir SAC通过氧机制工作,提供超越传统OER催化限制的新途径.
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