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Updated: Jun 11, 2025

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Pd-催化C(sp2) -C(sp3) 苏苏基合和合成使用设计的单氨酸联体的Lumacaftor

Xiangdong Zhang1, Fushun Jia1, Xu Guo1

  • 1Inner Mongolia Key Laboratory of Fine Organic Synthesis, College of Chemistry and Chemical Engineering, Inner Mongolia University (South Campus), 24 Zhaojun Road, Hohhot 010030, China.

Organic letters
|October 9, 2024
PubMed
概括

新型素连接体L1和L2使得高效的催化苏苏基合反应成为可能. 这些配体促进C(sp2) -C(sp3) 键的形成,导致药物合成的高产量.

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Cycloaddition Reactions: MO Requirements for Thermal Activation01:16

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Thermal cycloadditions are reactions where the source of activation energy needed to initiate the reaction is provided in the form of heat. A typical example of a thermally-allowed cycloaddition is the Diels–Alder reaction, which is a [4 + 2] cycloaddition. In contrast, a [2 + 2] cycloaddition is thermally forbidden.
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