新型混合/六酸微立方体,用于水性混合超级电容器,具有协同效应
Vu Van Thuy1,2, Nguyen Si Hieu3, Tran Viet Thu1
1Department of Physics and Chemical Engineering, Le Quy Don Technical University, 236 Hoang Quoc Viet, Hanoi 100000, Vietnam. thutv@mta.edu.vn.
Dalton transactions (Cambridge, England : 2003)
|October 10, 2024
概括
混合-六二二 (Ni-Co-HCF) 微立方体表现出增强的电化学性能. Ni1Co2-HCF材料表现出优异的特异性和稳定性,突出了其用于先进水性超级电容器的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术纳米技术
背景情况:
- 将不同金属结合在协调化合物中可以增强材料的性能.
- 六酸酸盐是用于储能应用的有希望的材料.
研究的目的:
- 为了合成和表征混合 - 合金六酸 (Ni-Co-HCF) 微立方体.
- 为了研究它们的材料和电化学特性,用于超级电容器应用.
主要方法:
- Ni-Co-HCF微立方体的共同沉合成,具有不同的摩尔比率.
- 综合材料表征. 综合材料表征.
- 在水性电解质中评估电化学性能.
主要成果:
- Ni-Co-HCF微立方体具有电池类型的电化学能量存储机制.
- Ni1Co2-HCF微立方体实现了最高的特定容量 (134 mA h g−1 或 1068 F g−1 在 1 A g−1).
- 使用Ni1Co2-HCF的非对称超级电容器装置显示出高能量密度 (74.4μW h cm−2) 和出色的循环稳定性 (2000个循环后87.7%的容量保留).
结论:
- 在Ni和Co位点之间的协同作用提高了电化学性能.
- 混合金属六二酸盐显示出作为水性超级电容器的高性能电极的巨大潜力.
- 1Co2-HCF是耐用和高效的储能设备的有希望的候选者.
更多相关视频
08:59Synthesizing a Gel Polymer Electrolyte for Supercapacitors, Assembling a Supercapacitor Using a Coin Cell, and Measuring Gel Electrolyte Performance
Published on: November 30, 2022
4.4K
07:57Author Spotlight: A Rapid, Microwave-Assisted Hydrothermal Synthesis Of Nickel Hydroxide Nanosheets
Published on: August 18, 2023
1.8K
相关概念视频
Valence Bond Theory
8.9K
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
8.9K
Ion Exchange
1.6K
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
1.6K
Ionic Association
216
The ionic association is the association of oppositely charged ions in an electrolyte solution to form ion pairs. Bjerrum defined ion pairs as two oppositely charged ions whose electrostatic attraction exceeds the thermal energy of the system, typically expressed as 2kT. Electrostatic attraction depends on ionic charge, separation distance, and the dielectric constant of the medium. Thermal energy, represented by kT, reflects the tendency of ions to move independently due to molecular motion.
216
Concentration Cells
205
A concentration cell is an electrochemical cell in which the emf arises from a difference in concentration of a species between two half-cells. Unlike galvanic cells, where electrical energy comes from a chemical reaction, the driving force here is the transfer of matter from a region of higher concentration to lower concentration. The overall process is therefore physical in nature. A classic illustration is a cell made of two chlorine electrodes operating at different chlorine gas...
205
Micelles
364
Micelle formation is an intricate process that hinges on the properties of amphiphilic or amphipathic molecules and the conditions of the system in which they are found. Amphiphilic molecules, which have both hydrophilic (water-attracting) and hydrophobic (water-repelling) parts, play a critical role in this process.In aqueous environments, these molecules arrange themselves such that their hydrophilic heads are turned towards the water phase, while their hydrophobic tails are oriented away...
364
Superplasticizers
468
Superplasticizers are advanced admixtures that enhance the workability of concrete by lowering the water content without compromising the strength of the material. These substances are highly effective water reducers, improving concrete flow, making it easier to work with, and enabling concrete to reach inaccessible areas or densely reinforced sections without mechanical vibration. The key components in superplasticizers are either sulfonated melamine or naphthalene formaldehyde condensates,...
468
