调节灵活的多孔宿主中的光物理性质,通过调节客辅助的电荷转移相互作用来调节
Rohan Jena1, Faruk Ahamed Rahimi1, Tarak Nath Das2
1Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, School of Advanced Materials (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur Post, Bangalore-560064, India. tmaji@jncasr.ac.in.
概括
我们在以为基础的多孔协调聚合物 (PCP-1) 中创建了电子捐赠-接受分子的1D数组. 这些材料表现出电荷转移辐射,这对于光伏和光电子设备很重要.
科学领域:
- 材料科学 材料科学 材料科学
- 超分子化学 超分子化学
- 太阳能光伏发电是如何实现的
背景情况:
- 电子捐赠者-接受器染色体的1D阵列对于先进的应用至关重要.
- 多孔协调聚合物 (PCP) 为分子组装提供可调的框架.
研究的目的:
- 构建和描述由电子捐赠-接受分子协调驱动的1D数组.
- 在基于Zn的PCP中研究这些数组的光物理性质.
主要方法:
- 一种基于Zn的多孔协调聚合物 (PCP-1) 的合成,该聚合物包含一个*o*-phenanthroline受体.
- 封装各种电子捐赠的客分子 (,碳醇,二福,二西欧芬).
- 单晶结构的确定和光物理特性 (排放研究).
主要成果:
- 在PCP-1中成功形成了1D捐赠-接受分子阵列.
- 在所有客体封装PCP中观察到电荷转移排放.
- 计算了刺激子的结合能量,并将它们与客人的电子捐赠强度相关联.
结论:
- 在PCP中以协调驱动的自我组装可以创建功能性的1D捐赠者-接受器数组.
- 通过修改电子捐赠客分子,可以调整电子性质,特别是激电结合能量.
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