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Superconductor01:24

Superconductor

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A substance that reaches superconductivity, a state in which magnetic fields cannot penetrate, and there is no electrical resistance, is referred to as a superconductor. In 1911, Heike Kamerlingh Onnes of Leiden University, a Dutch physicist, observed a relation between the temperature and the resistance of the element mercury. The mercury sample was then cooled in liquid helium to study the linear dependence of resistance on temperature. It was observed that, as the temperature decreased, the...
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Network Covalent Solids02:18

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
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Electrical Conductivity01:13

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In perfect conductors, the electric field inside is always zero due to the abundance of free electrons, which nullify any field by flowing. As a result, any residual charge resides on the surface.
In a practical conductor, an applied electric field may be sustained, causing a flow of electrons, which produce a current. The differential form of the current, the current density, is related to the electric field.
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There is variation in the electrical conductivity of materials - metals, semiconductors, and insulators that are showcased with the help of the energy band diagrams.
Metals such as copper (Cu), zinc (Zn), or lead (Pb) have low resistivity and feature conduction bands that are either not fully occupied or overlap with the valence band, making a bandgap non-existent. This allows electrons in the highest energy levels of the valence band to easily transition to the conduction band upon gaining...
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Types Of Superconductors01:28

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A superconductor is a substance that offers zero resistance to the electric current when it drops below a critical temperature. Zero resistance is not the only interesting phenomenon as materials reach their transition temperatures. A second effect is the exclusion of magnetic fields. This is known as the Meissner effect. A light, permanent magnet placed over a superconducting sample will levitate in a stable position above the superconductor. High-speed trains that levitate on strong...
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硬铜化物具有特殊的导电性.

Ming-Xing Huang1,2, Changzeng Fan1, Bo Xu1

  • 1Center for High Pressure Science, State Key Laboratory of Metastable Materials Science and Technology, <a href="https://ror.org/02txfnf15">Yanshan University</a>, Qinhuangdao 066004, China.

Physical review letters
|October 11, 2024
PubMed
概括
此摘要是机器生成的。

研究人员使用高压合成了新型的结晶 (Cu_{2-δ}B_{25}). 这些异常坚硬和导电材料具有独特的电子特性,为先进的应用铺平了道路.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 固态化学 固态化学
  • 凝聚物质物理学 凝聚物质物理学

背景情况:

  • 在环境压力下,铜与的反应很少发生,对铜化合物的数据有限.
  • 现有的文献往往缺乏精确的固体测量对铜合材料.

研究的目的:

  • 为了合成和表征具有定义的固态度的新型铜化合物.
  • 研究合成材料的结构,机械和电子特性.

主要方法:

  • 使用铜和β-面前体的高压融方法.
  • 单晶X射线衍射用于结构分析.
  • 维克斯硬度测试和电导度测量.
  • 霍尔测量以确定导电类型和压力依赖.

主要成果:

  • 成功合成了 Cu_{2-δ}B_{25} 单晶 (δ∼0.03) 与四边形子网.
  • 实现了高维克尔硬度 (26.5 GPa) 和记录电导率 (1.19×10^5 S/m) 的二元象面基化物.
  • 观察到一个压力诱导的p-n导电型转换在30GPa左右.

结论:

  • Cu_{2-δ}B_{25} 是一种具有特殊电导性的超硬材料的新类.
  • 观察到的电子性质是潜在的调整铜含量和价值状态.
  • 这项工作为技术应用提供了调节丰富化合物的电子性能的新可能性.