在异质双位触媒中视觉化取决于距离的协同作用
Shuaiwei Jiang1, Jiawei Xue1, Tong Liu1,2
1School of Nuclear Science and Technology, Key Laboratory of Precision and Intelligent Chemistry, Hefei National Research Center for Physical Sciences at the Microscale, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, P.R. China.
Journal of the American Chemical Society
|October 11, 2024
概括
在双位点催化剂中优化界面 (OH) 距离可以增强协同催化. 正确的间距是有效的反应物脱质和高催化活性的关键,正如酸氧化所示.
科学领域:
- 电化学
- 催化剂
- 表面科学
背景情况:
- 界面基 (OH) 组对于固体/液体界面的协同催化是至关重要的.
- 了解OH与反应物之间的空间关系是具有挑战性的,但对于反应动力学至关重要.
研究的目的:
- 在异质双位点催化中可视化和量化界面OH的距离依赖协同效应.
- 根据其与活性位点的距离,阐明OH在反应物脱质中的作用.
主要方法:
- 使用 ex-situ 红外纳米光谱和 in-situ 红外光谱.
- 研究的双位点催化剂具有调制的Rh (Ir-Co) 和Ruthenium (Ir-Ru) 双距离.
主要成果:
- 证明OH可促进脱质,其效率取决于位置的距离.
- 确定了7.9 Å的最佳Ir-Co距离,以实现高效的协同作用,与动态OH平衡相关.
- 由于OH积累,在不理想的距离下观察到减少的协同作用.
结论:
- 建立了空间距离和催化活动 (质量活动) 之间的普遍火山形关系.
- 突出了动态平衡和空间距离对于协同催化作用的重要性,适用于各种氧性金属.
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