通过二进制间隔器和单晶协调,有效的拉德尔斯登-波珀矿太阳能电池的统一相变换
Zijia Li1,2, Hao Gu3, Xiaolong Liu4
1MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, National Innovation Platform (Center) for Industry-Education Integration of Energy Storage Technology, Xi'an Jiaotong University, Xi'an, 710049, P. R. China.
Advanced materials (Deerfield Beach, Fla.)
|October 12, 2024
概括
二进制间隔器通过增强结晶和载体运输来改善二维拉德尔斯登 - 波珀矿 (RPP) 太阳能电池. 这导致RPP的记录功率转换效率 (PCE) 和开通电路电压 (VOC).
科学领域:
- 材料科学 材料科学 材料科学
- 可再生能源可再生能源是可再生能源.
- 太阳能光伏发电是如何实现的
背景情况:
- 2D Ruddlesden-Popper矿 (RPPs) 提供了环境稳定性,但与3D矿相比,其功率转换效率 (PCE) 较低.
- 较差的载体传输和异质相限制了RPP太阳能电池的性能.
研究的目的:
- 通过改善载体运输和电影质量来提高RPP太阳能电池的PCE.
- 研究二进制间隔器对RPP膜中的结晶动力学和相位分布的影响.
主要方法:
- 引入二进制间隔剂 (n-丁,BA和胺,PFA) 来调节RPP薄膜结晶.
- 使用n = 5个BA2MA4Pb5I16内存单晶用于阶段式载体运输.
- 制造高质量的 (BA0.75PFA0.25) 2MA4Pb5I16 薄膜.
主要成果:
- 实现了统一的相位变换和高质量的RPP片.
- 在低和高n值阶段之间展示了超快的阶段式载体运输.
- 抑制非辐射重组和改善载体提取.
结论:
- 二进制间隔器和单晶辅助结晶显著提高了RPP膜的质量.
- 开发的RPP太阳能电池实现了21.15%的PCE和1.26V的VOC的记录冠军,n ≤5.
- 这项工作为低n值RPP太阳能电池设定了新的基准.
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