在元素的定量确定中分析不确定性的评估 - - 的案例
Takehiro Sumita1, Takahito Osawa2, I-Huan Chiu2
1Department of Materials, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka-shi, 819-0395, Fukuoka, Japan.
Analytica chimica acta
|October 13, 2024
概括
本研究介绍了一种近乎绝对的方法来评估元素分析中的分析不确定性. 快速马射线分析 (PGA) 和感应合等离子光辐射光谱法 (ICP-OES) 用于量化,展示了强大的定量分析的新方法.
科学领域:
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
背景情况:
- 定量分析的质量取决于不确定性评估 (准确性和精度).
- 当前的方法经常评估相对于相同的分析技术的不确定性.
- 对于更全面的不确定性评估,建议采用准绝对方法.
研究的目的:
- 调查用于量化的快速马射线分析 (PGA) 的分析不确定性.
- 评估用于分析的感应合等离子光学发射光谱学 (ICP-OES) 的适用性.
- 开发一种近乎绝对的方法来评估分析不确定性.
主要方法:
- 使用了快速马射线分析 (PGA),一种具有最小化学干扰的方法.
- 采用感应合等离子光学发射光谱法 (ICP-OES) 进行比较分析.
- 分析了各种含材料 (CrB2,B4C,钢-B4C融) 以评估不确定性.
主要成果:
- PGA准确地确定了的数量,与真实值相对应得很好.
- 通过比较PGA和ICP-OES结果,有效评估了分析不确定性.
- 在这两种方法中,通过优化样本准备,确定和最小化了两种方法的关键不确定性来源.
结论:
- 分析不确定性的准绝对评估是可行的,使用一种无化学干扰的技术,如PGA.
- 这种新的概念超越了PGA和ICP-OES,适用于各种分析方法和元素.
- 拟议的方法为分析化学提供了一个广泛有益的框架,提高了定量分析的质量.
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