含有Ce的ABO矿中的欧特体分解:第一部分,CeAlO合作生长的案例
Aaron C Johnston-Peck1, Russell A Maier1
1Material Measurement Laboratory, National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, MD 20899 United States.
概括
矿氧化氧化物 (CeAlO) 的氧化导致其转化为氧化物 (CeO2) 和氧化物 (AlO3). 微观结构板状膜的形成和大小可以通过加工条件和回火来控制.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 陶制品 在陶方面.
背景情况:
- 矿材料表现出复杂的相位行为.
- 了解氧化机制对于材料的稳定性至关重要.
- 氧化 (CeAlO3) 是一种具有潜在应用的矿.
研究的目的:
- 为了研究CeAlO3的氧化和eutectoid转化.
- 为了表征得到的微观结构和相位产品.
- 探索处理对转换动力学和形态学的影响.
主要方法:
- 热重力测量分析 (TGA) 用于监测质量变化.
- 用X射线衍射 (XRD) 来进行相位识别.
- 扫描传输电子显微镜 (STEM) 用于微观结构分析.
主要成果:
- 证实了CeAlO3转化为CeO2和Al2O3的状体转化.
- 观察到的状微结构表明了合作增长.
- 形成了纳米尺度的片,在高温回火时变粗.
结论:
- CeAlO3的氧化导致了一个可预测的eutectoid分解.
- 微观结构的演变,包括叶片大小,可以通过热处理进行调整.
- 控制合成为量身定制的陶复合材料提供了潜力.
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