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Updated: Jun 10, 2025

Efficient Synthesis of Polyfunctionalized Benzenes in Water via Persulfate-promoted Benzannulation of α,β-Unsaturated Compounds and Alkynes
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Efficient Synthesis of Polyfunctionalized Benzenes in Water via Persulfate-promoted Benzannulation of α,β-Unsaturated Compounds and Alkynes

Published on: December 16, 2019

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基碳素酸的正式转化为醇

Chenhao Lou1, Qiuwei Huang1, Leiyang Lv1

  • 1Key Laboratory of Advanced Light Conversion Materials and Biophotonics, School of Chemistry and Life Resources, Renmin University of China, Beijing, 100872, People's Republic of China.

Chemistry (Weinheim an der Bergstrasse, Germany)
|October 14, 2024
PubMed
概括

这项研究提出了一种新的方法,利用光催化剂从基碳酸化合物中合成. 这种高效的工艺为现有的合成途径提供了一种温和的替代方案.

关键词:
碳氧酸是碳氧酸中的一种.子的重新排列方式过氧化过氧化过程烯 (Phenol) 是一种类型的.光催化作用的光催化

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Benzene to Phenol via Cumene: Hock Process

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In the presence of oxidizing agents, phenols are oxidized to quinones. Quinones can be easily reduced back to phenols using mild reducing agents. The electron-donating hydroxyl group enhances the reactivity of the aromatic ring, enabling oxidation of the ring even in the absence of an α hydrogen.
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox...
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