在商用粒子原子层沉积系统中合成的Pt/C催化剂,可提高燃料电池的耐用性
Fiona Pescher1,2,3,4, Julian Stiegeler1,4, Philipp A Heizmann1,2,4
1Electrochemical Energy Systems, Laboratory for MEMS Applications, IMTEK - Department of Microsystems Engineering, University of Freiburg Georges-Koehler-Allee 103 79110 Freiburg Germany.
RSC advances
|October 15, 2024
概括
粒子原子层沉积 (ALD) 提供了一种可扩展的方法,用于为燃料电池制造高性能/碳 (Pt/C) 电催化剂. 这些ALD合成的催化剂在苛刻的操作条件下表现出增强的耐用性和稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 粒子原子层沉积 (ALD) 是用于3D材料合成的新兴技术.
- 开发高效且耐用的电催化剂对于推进燃料电池技术至关重要.
研究的目的:
- 使用可扩展粒子ALD系统合成/碳 (Pt/C) 电催化剂.
- 评估ALD合成的Pt/C催化剂的性能和耐用性,用于燃料电池应用.
主要方法:
- 使用商业粒子ALD系统进行Pt/C电催化剂合成.
- 使用传输电子显微镜 (TEM) 和X射线衍射 (XRD) 描述了催化剂的特性.
- 通过加速降解测试,与最先进的催化剂进行基准催化剂性能和耐用性比较.
主要成果:
- 获得高度分散的纳米颗粒,尺寸分布狭窄 (2.2-2.6 nm).
- 合成ALD的催化剂的初始性能与商业基准相比较.
- 经过证明的优越耐用性,在3万个循环后,电化学活性表面积高达64%,电流密度保持率高达34%.
结论:
- 粒子ALD是一种可扩展和有效的方法,用于生产先进的燃料电池电催化剂.
- 合成ALD的Pt/C催化剂在耐用性和性能保持方面提供了显著的改进.
- 这种方法对工业规模的燃料电池催化剂制造具有前景.
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