在EU-和Er-激活的CaF2中进行光学/热敏多模式发光,用于高安全防伪
Chenxi Bian1, Ting Wang1,2, Xuanyu Zhu1
1College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China.
ACS applied materials & interfaces
|October 15, 2024
概括
这项研究开发了一种新型的防伪材料,使用化 (CaF2) . 该材料表现出多色发光和对温度敏感的特性,用于先进的安全应用.
科学领域:
- 材料科学 材料科学 材料科学
- 发光的光度是非常的低.
- 纳米技术 纳米技术
背景情况:
- 越来越需要先进的防伪措施,推动研究具有独特光学特性的材料.
- 多模式发光材料为信息存储和身份验证提供了增强的安全功能.
研究的目的:
- 为多式联网光学输出设计一种用欧 (Eu) 和 (Er) 离子编的CaF2.
- 调查材料的潜力,作为一个强大的防伪解决方案,具有动态的反应.
主要方法:
- 与Eu3+和Er3+离子配合CaF2进行合.
- 分析了Eu3+到Eu2+的自我还原及其对发光效应的影响.
- 研究温度依赖的发光和向上转换特性.
- 开发一个三路身份验证模型.
主要成果:
- 由于Eu2+/Eu3+的共存,通过变化的激发波长 (300-335nm) 从色到蓝色发光实现了颜色转换.
- 已证明可见的温度敏感发光,具有高的热灵敏度 (Sa = 0.0156 K-1,Sr = 0.83%K-1).
- 通过调整Er3+度,启用了可调色上升转换发光.
结论:
- 开发的CaF2体对激发波长和温度表现出动态的多色响应.
- 欧元和欧元的协同整合创造了一个高效的三路身份验证模型.
- 这种多式发光材料为增强信息安全提供了通用和强大的防伪策略.
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