作为具有含量阴极的2S的酸盐中介氧化,用于具有极低超电位的硫电池
Jialing Wu1, Hualin Ye2, Yongpan Hu3
1Macao Institute of Materials Science and Engineering (MIMSE), MUST-SUDA Joint Research Center for Advanced Functional Materials, Macau University of Science and Technology, Taipa, Macao, 999078, China.
Advanced materials (Deerfield Beach, Fla.)
|October 15, 2024
概括
乙基酸盐 (LiEX) 作为一种高效的氧化还原媒介,降低硫化物 (Li2S) 在硫电池中的氧化潜力. 这一突破使先进的电池技术能够实现更高的能量密度和更好的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 硫化 (Li2S) 是用于高能量密度硫 (Li-S) 电池的有前途的阴极材料.
- 直接氧化Li2S会导致高超电位和低能效.
- 氧化还原介质可以加速Li2S转换,但通常具有不合适的氧化还原潜力.
研究的目的:
- 为了确定一个有效的氧化还原媒介,以适合的氧化还原潜力为Li2S氧化.
- 为了提高Li-S电池中基于Li2S的阴极的电化学性能.
主要方法:
- 在室温下从Li2S,乙醇和CS2中合成乙酸盐 (LiEX).
- 调查LiEX作为Li2S氧化过程中的氧化还原媒介.
- 在Li-S电池的并联催化方案中,将LiEX与Ni-NC催化剂集成.
主要成果:
- 发现LiEX是一种高效的氧化还原媒介,其氧化还原潜力 (≈2.3 V vs Li+/Li) 接近Li2S氧化潜力 (2.25 V vs Li+/Li).
- LiEX显著降低了Li2S的氧化潜力,从3.6V降至2.3V,提高了反应动力学.
- 双联催化系统在0.2 mA cm-2和1400个周期下实现了≈1100 mAh g-1的特定容量,容量保持率为73%.
结论:
- 乙基酸盐 (LiEX) 是一种新且有效的 Li2S 阴极的氧化还原介质.
- 开发的并联催化系统展示了Li-S电池的卓越性能,优于现有的Li2S基材料.
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