三氧化离子[OF3]-:对二进制,高价氧氧物种的光谱证据
Deniz F Meyer1, Robert Medel1, Sebastian Riedel1
1Freie Universität Berlin, Fachbereich Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie-Anorganische Chemie, Fabeckstr. 34/36, 14195, Berlin.
Angewandte Chemie (International ed. in English)
|October 15, 2024
概括
研究人员报告了超价三氧酸盐离子[OF3]-.的第一个实验证据. 这一发现扩大了涉及第二排元素的高价值化合物的已知的化学成分.
科学领域:
- 无机化学 无机化学 有机化学
- 超价化合物 超价化合物 超价化合物
- 化学 的化学
背景情况:
- 对第二排元素的高价值化合物的实验证据有限.
- 三氧化离子[OF3]-一直是一个长期寻求的物种.
研究的目的:
- 报告了超价三氧化酸盐离子[OF3]-.的第一个实验合成和表征.
- 用理论和实验方法研究[OF3]-的结构和结合.
主要方法:
- 在冷条件下将[OF3]-分离到固体虹矩阵中.
- 氧二化物与通过激光切除产生的离子的反应.
- 富里埃变换红外 (FTIR) 光谱学与同位素标记.
- 计算化学方法包括VSEPR理论和合集群计算 (CCSD).
主要成果:
- 成功地分离和表征了双重高价三氧化二元离子[OF3]-.
- 实验证实[OF3]-.对预测的C2v对称T形结构的实验证实.
- 光谱和计算分析揭示了一个短和两个长的O-F债券,与2c-2e和3c-4e结合一致.
- 对MOF2物种的观察,被确定为接触离子对M+[OF2]•-.
结论:
- [OF3]-的合成和表征代表了超价化学的重大进步.
- [OF3]-的稳定性与相关的[OF2]•-基离子的稳定性有关.
- 这项工作提供了关键的实验数据,以了解超价主要组化合物的结合.
相关概念视频
Lewis Structures of Molecular Compounds and Polyatomic Ions
34.6K
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
34.6K
Exceptions to the Octet Rule
27.7K
Many covalent molecules have central atoms that do not have eight electrons in their Lewis structures. These molecules fall into three categories:
27.7K
Ionic Bonding and Electron Transfer
41.3K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
41.3K
The Aufbau Principle and Hund's Rule
46.6K
To determine the electron configuration for any particular atom, we can build the structures in the order of atomic numbers. Beginning with hydrogen, and continuing across the periods of the periodic table, we add one proton at a time to the nucleus and one electron to the proper subshell until we have described the electron configurations of all the elements. This procedure is called the aufbau principle, from the German word aufbau (“to build up”). Each added electron occupies the...
46.6K
Hybridization of Atomic Orbitals II
31.9K
sp3d and sp3d 2 Hybridization
31.9K
Resonance
53.2K
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N-O and N=O bonds.
53.2K


