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在MoO中的新型Eu3+-合眼镜-WO3-La2O3-B2O3系统:制备,结构和光发光特性
Lyubomir Aleksandrov1, Margarita Milanova1, Aneliya Yordanova1
1Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, G. Bonchev, str. bld. 11, 1113 Sofia, Bulgaria.
Molecules (Basel, Switzerland)
|October 16, 2024
概括
氧化物 (Eu2O3) 合的新型多元玻璃显示出有希望的红光发射特性. 增加氧化 (WO3) 含量会增强光发光,表明它们作为光学应用中的高效红色光体的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 发光的光度是非常的低.
背景情况:
- 多元组件玻璃正在探索先进的光学应用.
- 和氧化物是影响玻璃性能的关键成分.
- 欧 (Eu3+) 的注对于的红色排放至关重要.
研究的目的:
- 为了合成和描述用Eu2O3合的新型 (50-x) MoO3:xWO3:25La2O3:25B2O3玻璃.
- 为了研究这些玻璃的结构,热,光学和发光特性.
- 评估它们作为红色发光光体的潜力.
主要方法:
- 玻璃合成的融化灭方法.
- 拉曼光谱,差异热分析 (DTA) 和光发光 (PL) 光谱用于属性评估.
- 紫外线吸收光谱和折射率测量用于光学特征.
主要成果:
- 玻璃表现出高的玻璃过渡温度.
- 拉曼光谱显示了四面体 (MoO4) 2和 (WO4) 2单位的存在,WO6八面体含量增加.
- 从Eu3+中观察到强烈的红色排放,PL强度随WO3含量增加而增加.
- 综合光强度比表明Eu3+离子占据非中心对称位置.
结论:
- 合成的玻璃具有有利的热和结构特性.
- 加入氧化可以增强 Eu3+ 合玻璃的发光性能.
- 这些玻璃是红光发射应用的有希望的候选者.
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