从akaganéite纳米颗粒中形成硬磁性epsilon铁氧化物阶段
Navya Joseph1, Surya Gopi1, Aladin Ullrich2
1Department of Physics, Cochin University of Science and Technology, Cochin 682022 Kerala, India.
Nanotechnology
|October 17, 2024
概括
合成了高强迫性的氧化铁纳米粒子. 在高温下炼铁氧化 (β-FeOOH) 诱导相变,显著提高磁强迫力.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 固态化学 固态化学
背景情况:
- 阿卡甘伊特 (β-FeOOH) 纳米颗粒对磁性应用有兴趣.
- 了解氧化铁的相位转换对于定制磁性质至关重要.
研究的目的:
- 为了研究β-FeOOH纳米粒子的温度诱导的相变.
- 为了将这些相位变化与磁性强制性相关联.
- 探索高强迫性材料的潜力.
主要方法:
- 通过使用FeCl3·6H2O和尿素的强制水解来制备延长的β-FeOOH纳米粒子.
- 在SiO2矩阵内稳定β-FeOOH.
- 在500°C至1300°C的温度下制样本.
主要成果:
- 在化过程中,β-FeOOH转化为γ-Fe2O3,然后转化为ε-Fe2O3
- -Fe2O3相形成导致强制性迅速增加,在1200°C时达到21.5kOe.
- 在1300°C时,ε-Fe2O3转化为α-Fe2O3,导致强制性显著下降.
结论:
- 温度诱导的β-FeOOH相变对于确定磁性属性至关重要.
- 铁氧化物纳米粒子中ε-Fe2O3阶段负责实现高强制性.
- 控制化提供了一种途径来调整基于氧化铁的纳米材料的磁性强制性.
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