通过氧硫酸盐激活增强西马зин降解,使用米的生物炭作为新型Fe/N-C催化剂
Aaron Albert Aryee1, Md Abdullah Al Masud2, Won Sik Shin3
1Department of Chemistry, College of Basic and Applied Sciences, University of Ghana, Legon, Ghana; School of Architecture, Civil, Environmental and Energy Engineering, Kyungpook National University, Daegu, 41566, Republic of Korea.
Chemosphere
|October 17, 2024
概括
一种新型的米生物炭有效降解水中的西马除草剂,使用过氧硫酸盐激活. 这种Fe/N-C催化剂显示出高效率,矿化和可重复使用,用于清除水污染物.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 催化剂是一种催化剂.
背景情况:
- 像西马зин (SIM) 这样的除草剂污染水生环境,造成生态风险.
- 有效的清除方法对于减轻水体中除草剂污染至关重要.
研究的目的:
- 为了合成胺合的米生物炭 (RBC@Hemin20%) 作为Fe/N-C催化剂.
- 为了评估其在降解西马的效率,使用过氧硫酸盐 (PMS).
主要方法:
- 一步热解用于RBC@Hemin20%的合成.
- 通过催化剂激活PMS进行西马降解.
- 激素清除和ESR光谱学以阐明降解机制.
- 对于中间毒性分析的ECOSAR软件.
主要成果:
- 在优化条件下达到>99%的西马降解.
- 确定了激素 (•OH,SO4•−) 和非激素 (1O2) 途径.
- 证明了高矿化 (97.3%) 和可重复使用 (~4个循环后74.1%).
- 在各种水类和其他污染物 (TC,DCF) 中有效降解.
结论:
- RBC@Hemin20%有效地激活PMS进行西马зин去除.
- 催化剂对各种水生有机污染物具有广泛的适用性.
- 这种生物质衍生的Fe/N-C复合物为水资源整治提供了一个有前途的解决方案.
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