具有两光子协同作用的颜色变化和它们的信息加密应用的离子联有机框架
Bin Zhou1, Li-Hui Cao1, Bing-Sha Li1
1Shaanxi Key Laboratory of Chemical Additives for Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an, Shaanxi 710021, People's Republic of China.
ACS applied materials & interfaces
|October 18, 2024
概括
新的光色结有机框架 (HOF) 具有可调的双发光,用于先进的信息加密. 这些材料在紫外线下改变颜色并发射红色光,从而使数据存储应用安全.
科学领域:
- 材料科学 材料科学 材料科学
- 超分子化学 超分子化学
- 摄影化学的使用.
背景情况:
- 光色结有机框架 (HOF) 为信息加密等应用提供可调节的发光.
- 开发具有可控多种颜色变化的HOF需要整合多种发光功能组.
研究的目的:
- 构建具有双发光功能组的可切换的新型光色和光发光HOF.
- 为了研究控制色彩变化和发光性质的HOF中的协同效应.
- 探索这些HOF在信息加密中的实际应用.
主要方法:
- 使用N,N'-bis(2-phenylalanine) -1,4,5,8-naphthalenediimine (H2PheNDI) 和碳胺胺 4,4'-azobis(化物) (AZBH) 的HOFs (iHOF-41) 的合成.
- 在365nm紫外线照射下对光色特性进行表征.
- 对光发光特性和光异构化速率的评估.
- 复合膜的制造用于应用测试.
主要成果:
- 合成的iHOF-41在15分钟的365nm紫外线照射后,呈现出从色红色到黑色的颜色变化.
- 在连续5小时的紫外线照射下,在晶体溶液中达到接近99%的光异构化率.
- 在紫外线暴露时,复合膜中证明了同时的光色和红色光发射.
- 成功构建了基于可切换的双发光功能组的HOF.
结论:
- 该研究成功开发了具有可切换双发光的HOF,证明了信息加密的潜力.
- 研究了光异构化和光色化之间的协同机制.
- 这些发现强调了这些先进的HOF在实际信息安全应用中的实用性.
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