在处理过的芯片和水样中进行状助散低密度液体-液体微提取,用于气色谱分析
Anuwat Ratsamisomsi1,2, Chookiat Khongsiri1, Prapin Wilairat3
1Department of Chemistry, Thammasat University, Khlong Luang, Pathumthani, Thailand.
概括
一种新方法使用醇衍生物和分散液液微提取,有效地检测加工食品中的可能致癌物烯胺. 在所有分析的食品样本中都发现了烯胺,其中一些超过了安全限值.
科学领域:
- 分析化学 分析化学
- 食品化学 食品化学
- 环境科学 环境科学
背景情况:
- 烯胺是热加工食品和环境污染物中可能存在的人类致癌物.
- 对烯胺的分析需要有效的样本提取和预缩技术.
研究的目的:
- 开发和验证一种用于确定烯胺的新方法.
- 分析加工食品样本和水中的烯胺含量.
主要方法:
- 样品的准备过程包括脱脂,沉和过.
- 在50°C的酸性甲醇中使用xanhydrol的烯胺衍生物化.
- 散布液体-液体微提取用无离子,然后进行气色谱-质谱 (GC-MS) 分析.
主要成果:
- 该方法表现出极好的线性 (R2>0.9997),精度 (<10%RSD) 和恢复 (84107%).
- 量化极限为食品的210μg kg−1和水的0.050.10 μg L−1.
- 在所有加工的芯片样本中检测到烯胺,其中一些超过750μg kg-1;在水样中没有发现.
结论:
- 开发的方法对复杂矩阵中的烯胺分析具有敏感性和效率.
- 由于含有烯胺,加工食品带来了显著的饮食暴露风险.
- 分析的环境水样本中没有含有可检测到的烯胺水平.
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