对深度转移稳定的硬球体流体的结构,热力学和剪切弹性的理论分析
Subhasish Chaki1,2,3, Baicheng Mei1,2, Kenneth S Schweizer1,2,4
1Department of Materials Science, <a href="https://ror.org/047426m28">University of Illinois at Urbana-Champaign</a>, Urbana, Illinois 61801, USA.
Physical review. E
|October 19, 2024
概括
这项研究揭示了对玻璃形成液体在其转移稳定状态的行为的新见解. 我们发现了独特的结构,热力学和动态特性,提高了我们对这些复杂材料的理解.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 统计力学 统计力学
- 材料科学 材料科学 材料科学
背景情况:
- 对于材料科学来说,了解在元稳定状态下形成玻璃的流体至关重要.
- 它们的结构,热力学和动力学提出了重大的理论挑战.
研究的目的:
- 研究深度转移稳定的硬球体流体的结构相关性,热力学特性和动态弹性剪切模量.
- 统一研究这些属性的理论方法.
主要方法:
- 微观平衡液态积分方程理论的应用.
- 纳入原始模式合理论用于粒子定位.
主要成果:
- 预测对关键性质 (如对相关函数和压力) 的分歧逆临界功率定律.
- 在对相关函数中观察分秒峰值和抑制的间歇配置.
- 确定动态弹性模块的两个不同的指数增长模式.
结论:
- 这些发现与现有的模拟和实验数据保持一致.
- 建立了密度波动,可压缩性,局部结构和弹性模量之间的新理论联系.
- 这些见解广泛适用于合体悬浮液和超冷液体.
相关概念视频
Thin-Walled Hollow Shafts
169
In analyzing a thin-walled hollow shaft subjected to torsional loading, a segment with width dx is isolated for examination. Despite its equilibrium state, this segment faces torsional shearing forces at its ends. These forces are quantitatively described by the product of the longitudinal shearing stress on the segment's minor surface and the area of this surface, leading to the concept of shear flow. This shear flow is consistent throughout the structure, indicating a uniform distribution...
169
Elastic Strain Energy for Shearing Stresses
165
As discussed in previous lessons, strain energy in a material is the energy stored when it is elastically deformed, a concept crucial in materials science and mechanical engineering. This energy results from the internal work done against the cohesive forces within the material. When a material undergoes shearing stress and corresponding shearing strain, the strain energy density, which is the energy stored per unit volume, is calculated. Within the elastic limit, where the stress is...
165
Characteristics of Fluids
3.8K
When a force is applied parallel to the top surface of a solid, it resists the applied force due to the internal frictional forces between the layers of the solid known as shearing resistance. However, when the force is removed, the shearing forces restore the original shape of the solid. Other deformation forces also cause temporary changes in shape if the forces are not beyond a threshold magnitude. Solids tend to retain their shape, making the study of their rest and motion easier. Beyond...
3.8K
Structures of Solids
14.0K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
14.0K
Intermolecular Forces and Physical Properties
20.4K
20.4K
Newtonian Fluid: Problem Solving
199
Newtonian fluids exhibit a constant viscosity, meaning their shear stress and shear strain rate are directly proportional. This property ensures a predictable and stable response to applied forces, maintaining a linear relationship between force and flow. Examples include water, air, and light oils, consistently demonstrating this proportional behavior regardless of external conditions.
A velocity gradient forms within the fluid when a Newtonian fluid is placed between two parallel plates, with...
A velocity gradient forms within the fluid when a Newtonian fluid is placed between two parallel plates, with...
199


