Jove
Visualize
联系我们
JoVE
x logofacebook logolinkedin logoyoutube logo
关于 JoVE
概览领导团队博客JoVE 帮助中心
作者
出版流程编辑委员会范围与政策同行评审常见问题投稿
图书馆员
用户评价订阅访问资源图书馆顾问委员会常见问题
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experiments存档
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教师资源中心教师网站
使用条款与条件
隐私政策
政策

相关概念视频

Intermolecular Forces03:13

Intermolecular Forces

57.7K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
57.7K
Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

14.5K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.5K
Electrolytes: van't Hoff Factor03:08

Electrolytes: van't Hoff Factor

32.9K
Colligative Properties of Electrolytes
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
32.9K
Factors Affecting Activity Coefficient01:17

Factors Affecting Activity Coefficient

759
The extended Debye-Hückel equation indicates that the activity coefficient of an ion in an aqueous solution at 25°C depends on three partially interdependent properties: the ionic strength of the solution, the charge of the ion, and the ion size. 
The activity coefficient value for an ion is close to one when the solution has almost zero ionic strength, i.e., when the solution shows close to ideal behavior. As the ionic strength of the solution increases from 0 to 0.1 mol/L, a...
759
Osmosis and Osmotic Pressure of Solutions02:40

Osmosis and Osmotic Pressure of Solutions

39.4K
A number of natural and synthetic materials exhibit selective permeation, meaning that only molecules or ions of a certain size, shape, polarity, charge, and so forth, are capable of passing through (permeating) the material. Biological cell membranes provide elegant examples of selective permeation in nature, while dialysis tubing used to remove metabolic wastes from blood is a more simplistic technological example. Regardless of how they may be fabricated, these materials are generally...
39.4K
Intermolecular Forces in Solutions02:28

Intermolecular Forces in Solutions

33.1K
The formation of a solution is an example of a spontaneous process, a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
33.1K

您也可能阅读

相关文章

通过共同作者、期刊和引用图与本文相关的文章。

排序
Same author

A Unified Model to Predict Electrophoresis in Porous Media and Free Electrolytes.

Small (Weinheim an der Bergstrasse, Germany)·2025
Same author

Diffusiophoresis in porous media saturated with a mixture of electrolytes.

Nanoscale advances·2025
Same author

Hydromechanical Modulation of Enzymatic Kinetics Using Microfluidically Configurable Nanoconfinement Arrays.

ACS central science·2024
Same author

Diffusioosmotic flow reversals due to ion-ion electrostatic correlations.

Nanoscale·2024
Same author

Unidirectional drying of a suspension of diffusiophoretic colloids under gravity.

RSC advances·2023
Same author

Diffusiophoresis of a spherical particle in porous media.

Soft matter·2023

相关实验视频

Updated: Jun 10, 2025

Generation and Control of Electrohydrodynamic Flows in Aqueous Electrolyte Solutions
08:41

Generation and Control of Electrohydrodynamic Flows in Aqueous Electrolyte Solutions

Published on: September 7, 2018

8.8K

离子-离子静电相关性和水力动力滑动之间的竞争彻底改变了扩散大气层.

Shengji Zhang1, Henry C W Chu2

  • 1Department of Chemical Engineering, University of Florida Gainesville FL 32611 USA.

Chemical science
|October 21, 2024
PubMed
概括

一个新的模型预测了扩散大气,揭示了水力动力滑动和静电相关性如何相互作用. 这种竞争改变了离子运输,影响了从药物输送到石油回收的应用.

科学领域:

  • 物理化学 物理化学
  • 流体动力学 流体动力学
  • 电化学 电化学 电化学

背景情况:

  • 扩散层大气受水力动态滑动和静电相关关系的影响,但缺乏统一的预测模型.
  • 现有的理论单独解决这些因素,限制了对它们的结合效应的理解.

研究的目的:

  • 开发电荷道中扩散大气的数学模型,包括水力动态滑动和静电相关性.
  • 研究这些现象之间的相互作用及其对离子运输的影响.

主要方法:

  • 利用Navier的滑动条件来模拟通道壁上的水力动力滑动.
  • 使用修改后的Poisson方程来解释离子-离子静电相关性.
  • 在充电的平行板通道中计算了价值对称的电解质的扩散透性移动性.

主要成果:

  • 水力动力滑动可以推迟或消除因静电相关性引起的扩散透逆转,这取决于电解质价值.
  • 静电相关性显著限制水力动力滑动引起的移动性变化,减少滑动增强的离子运输高达60%或一个数量级.

结论:

  • 开发的模型提供了一个统一的框架,用于在合的水力动力学和静电效应下预测扩散大气.

更多相关视频

Merging Ion Concentration Polarization between Juxtaposed Ion Exchange Membranes to Block the Propagation of the Polarization Zone
08:06

Merging Ion Concentration Polarization between Juxtaposed Ion Exchange Membranes to Block the Propagation of the Polarization Zone

Published on: February 23, 2017

8.4K
AC Electrokinetic Phenomena Generated by Microelectrode Structures
20:38

AC Electrokinetic Phenomena Generated by Microelectrode Structures

Published on: July 28, 2008

11.5K

相关实验视频

Last Updated: Jun 10, 2025

Generation and Control of Electrohydrodynamic Flows in Aqueous Electrolyte Solutions
08:41

Generation and Control of Electrohydrodynamic Flows in Aqueous Electrolyte Solutions

Published on: September 7, 2018

8.8K
Merging Ion Concentration Polarization between Juxtaposed Ion Exchange Membranes to Block the Propagation of the Polarization Zone
08:06

Merging Ion Concentration Polarization between Juxtaposed Ion Exchange Membranes to Block the Propagation of the Polarization Zone

Published on: February 23, 2017

8.4K
AC Electrokinetic Phenomena Generated by Microelectrode Structures
20:38

AC Electrokinetic Phenomena Generated by Microelectrode Structures

Published on: July 28, 2008

11.5K
  • 这些发现对于理解自然过程和优化应用,如体分离,药物输送和增强石油回收至关重要.