纳米孔碳支持双金属 (Ni,Cu和Fe) -Mo催化剂用于生物柴油的部分化
Dolrudee Jaruwat1, Napat Kaewtrakulchai2, Siwat Siriorarnroj1
1Center of Excellence in Catalysis and Catalytic Reaction Engineering, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330, Thailand.
使用纳米孔碳催化剂升级生物柴油可提高燃料性能. 这种MoNi/NPC催化剂显著提高了大豆生物柴油的氧化稳定性和冷流性能.
科学领域:
- 催化剂是一种催化剂.
- 可再生能源可再生能源是可再生能源.
- 材料科学 材料科学 材料科学
背景情况:
- 与传统生物柴油相比,二代生物燃料如化脂肪酸甲基 (H-FAMEs) 提供了优越的燃料特性.
- 部分化是升级生物柴油的一个关键过程,改善了氧化稳定性和冷流等特性.
研究的目的:
- 评估从尾叶 (CL) 获得的纳米孔状碳作为生物柴油升级的催化剂支持.
- 合成和测试各种单金属和双金属催化剂,用于大豆生物柴油的部分化.
主要方法:
- 纳米多孔碳支物 (NPC) 是从尾叶合成的.
- 制备了单金属 (Mo/NPC,Ni/NPC,Ce/NPC,Fe/NPC) 和双金属 (MoNi/NPC,MoCu/NPC,MoFe/NPC) 催化剂.这些催化剂均为单金属 (Mo/NPC,Ni/NPC,Ce/NPC,Fe/NPC) 和双金属 (MoNi/NPC,MoCu/NPC,MoFe/NPC) 催化剂,它们均为两种类型的催化剂.
- 对大豆FAME的部分化进行了催化活性评估.
主要成果:
- 支持NPC的表面积很大 (1,323 m2g-1),促进了有效的催化剂活性位点分散.
- 摩尼/NPC催化剂表现出最高的催化活性.
- 关键的燃料性能得到了显著提高:氧化稳定性从3到14小时增加,云点从2到13°C,点从-1到10°C.
结论:
- 来自尾叶的纳米孔状碳是生物柴油升级中的催化剂的有希望的支持.
- 这种MoNi/NPC催化剂有效地提高了大豆生物柴油的氧化稳定性和冷流特性.
- 催化剂的选择对于生物柴油升级过程的经济可行性至关重要.
更多相关视频
08:40Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
12:08Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
Published on: June 24, 2022
相关概念视频
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
Reduction of Alkenes: Catalytic Hydrogenation
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation
Catalysis
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
