4.6V 离子电池的耐湿电解质
Nan Zhang1, Ai-Min Li1, Weiran Zhang1
1Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, MD, 20742, USA.
Advanced materials (Deerfield Beach, Fla.)
|October 23, 2024
概括
一种新的盐,氨三甲硫) 胺 (LiCTFSI),为高性能离子电池提供了更好的耐湿性和稳定性. 这种电解质使得在极端温度下能够稳健运行,性能优于商业电解质.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 商业离子电池电解质,如六酸 (LiPF6),由于氧化稳定性和湿度敏感性差,受到限制.
- 替代盐,如二三甲硫胺 (LiTFSI) 提高了耐水性,但在更高的电压下会导致电流收集器腐蚀.
研究的目的:
- 作为一种新型的,不腐蚀性和耐水分的电解质盐,引入烯三甲硫尼尔) 胺 (LiCTFSI).
- 评估基于LiCTFSI的电解质在高能离子电池中的性能,特别是使用NCM811.11等先进的阴极材料.
主要方法:
- LiCTFSI电解质配方的合成和表征.
- 使用LiNi0.8Co0.1Mn0.1O2 (NCM811) 阴极和石墨阳极对LiCTFSI电解质进行电化学测试.
- 在不同的温度条件 (-20°C至60°C) 和湿度水平 (高达2000ppm) 下的性能评估.
主要成果:
- 2.0 M LiCTFSI/乙烯碳酸盐 (PC) -乙烯碳酸盐 (FEC) 电解质对NCM811阴极 (500个循环) 和完整电池 (在500个循环后保持77.8%) 显示出出色的循环稳定性.
- 即使在2000ppm的湿度下,也保持了高循环稳定性,大大减少了严格干室条件的需要.
- 与商业LiPF6电解质相比,电解质可以使电池在广泛的温度范围内 (-20°C至60°C) 运行,在-20°C提供更高的性能,在60°C保持高容量.
结论:
- LiCTFSI是一种有前途的替代电解盐,可以克服传统LiPF6和LiTFSI的局限性.
- 开发的电解质在极端条件下提供了更高的安全性,耐用性和性能,为具有成本效益的高性能电池铺平了道路.
- 基于LiCTFSI的电解质适用于需要强大的能量储存解决方案的苛刻应用.
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