对环氧聚合物负热膨胀的设计和调制
Jiajun Li1, Zaiping Zou1, Yingsheng Lai1
1Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900, China.
ACS macro letters
|October 23, 2024
概括
研究人员使用新型固化剂DBCOD-NH2.2开发出具有负热膨胀 (NTE) 的环氧聚合物. 这一突破允许精确控制材料的热膨胀,这对于先进的应用至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
背景情况:
- 在环氧聚合物中实现受控热膨胀,特别是负热膨胀 (NTE),存在重大挑战.
- 在聚合物中调节热膨胀系数 (CTE) 的现有方法通常是有限的.
研究的目的:
- 开发一种有效的策略来制备具有NTE性能的环氧聚合物.
- 设计,合成和利用一种用于调节聚合物CTE的新型固化剂.
主要方法:
- 合成了一种基于二子环氧八二烯 (DBCOD) 的新型氨基基基因,DBCOD-NH2.
- DBCOD-NH2被用作各种商业环氧树脂的固化剂.
- 研究了控制热膨胀的结构属性关系.
主要成果:
- 合成的DBCOD-NH2有效地抑制了环氧聚合物中的热膨胀.
- 观察到显著的NTE性能,AFG90基聚合物中最显著的热收缩 (-43.6 ppm/K).
- 该NTE效应归因于DBCOD基因的形态转变和高交叉链密度.
结论:
- 该研究成功展示了一种在环氧聚合物中实现NTE的方法.
- 这些发现为定制CTE提供了对结构-属性相互作用的见解.
- 这项研究为开发具有精确调节的热膨胀特性的材料提供了一条途径.
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