在固定床离子交换反应堆中去除Per和Polyfluoroalkyl物质 (PFAS):决定PFAS吸收能力的因素和预测PFAS突破的模型
Lan Cheng1, Pingping Meng2, Detlef R U Knappe1
1Department of Civil and Environmental Engineering, North Carolina State University, Raleigh, 915 Partners Way, Raleigh, NC, 27695-7901, USA.
Water research
|October 23, 2024
概括
阳离子交换树脂有效地从水中去除和多基物质 (PFAS). 新的模型根据PFAS结构和水污染物 (如溶解有机物和酸盐) 预测PFAS的去除.
科学领域:
- 环境化学环境化学
- 水处理技术水处理技术
背景情况:
- 和多基基物质 (PFAS) 是持久性环境污染物,具有重大公共卫生问题.
- 阳离子交换 (IX) 是一个有前途的技术,用于从水中去除PFAS.
研究的目的:
- 量化PFAS结构和水矩阵成分对IX树脂吸收能力 (KIX) 的影响.
- 根据PFAS结构和水的特征,开发PFAS在IX列中的突破预测模型.
主要方法:
- 使用两个IX树脂和18个水矩阵进行了小规模的快速柱体测试.
- 为23个PFAS确定突破曲线和KIX值.
- 开发了一种使用正常化链长 (NCL) 的定量结构-属性关系 (QSPR) 来预测KIX.
主要成果:
- 溶解有机物 (DOM) 和酸盐对PFAS清除产生了负面影响.
- 在测试度下,化物,硫酸盐和二碳酸盐对KIX的影响是微不足道的.
- 开发了伪单溶物模型,使用NCL,总有机碳和酸盐度预测PFAS突破曲线.
结论:
- PFAS结构,DOM和酸盐是影响IX树脂性能的关键因素.
- 预测模型可以更好地设计和运行PFAS清除IX系统.
- NCL概念提供了一种可靠的方法来估计PFAS对IX树脂的亲和力.
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