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相关概念视频

Ion Exchange01:17

Ion Exchange

559
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
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Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.3K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.3K
Alkyl Halides02:45

Alkyl Halides

16.3K
Structural Properties
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
16.3K
Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

14.5K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.5K
Ions as Acids and Bases02:54

Ions as Acids and Bases

23.6K
Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
23.6K

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Extending the Lifespan of Soluble Lead Flow Batteries with a Sodium Acetate Additive
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用于水性化物流电池的软硬离子添加剂

Gyohun Choi1, Patrick Sullivan1, Xiu-Liang Lv1

  • 1Department of Materials Science and Engineering, University of Wisconsin-Madison, Madison, WI, USA.

Nature
|October 24, 2024
PubMed
概括

软硬齐特里离子捕获器 (SH-ZIT) 通过防止多化物问题,使稳定,高容量的水性氧化还原流电池成为可能. 这一突破允许高效的电网储能,

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科学领域:

  • 材料科学
  • 电化学
  • 可持续能源

背景情况:

  • 水性氧化还原流电池 (RFB) 对电网储能具有前景.
  • 基于化物的催化物因多化物形成而面临挑战,导致相分离,降低电荷状态 (SoC) 和设备故障.

研究的目的:

  • 在水性RFB中开发同质化物循环的新复合剂.
  • 克服聚化物形成的局限性,提高电池性能和寿命.

主要方法:

  • 作为多化物复合剂的软硬基捕获器 (SH-ZIT) 的设计和表征.
  • 使用化物催化物的SH-ZIT的流电池的电化学循环.
  • 在不同电荷和度下对多化物行为的研究.

主要成果:

  • SH-ZIT有效地复合聚化物,使水循环均.
  • 流电池在40 mA/cm2时表现出超过1000个循环的库伦比效率>99.9%,没有衰变.
  • 在高温下稳定运行,化物可达到90%的同质循环.
  • 证明了超高的催化剂容量利用率 (>120Ah/L在80%的SOC) 和与阳极的兼容性.

结论:

  • 在高性能水性RFB中,SH-ZIT有效地稳定化物催化物.
  • 这项技术显著提高了储能能力和循环寿命.
  • 在储能应用中探索先进的聚化物系统的新途径.