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相关概念视频

Colloids03:22

Colloids

17.4K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.4K
Colloidal precipitates01:09

Colloidal precipitates

518
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
518
Solubility03:00

Solubility

17.3K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
17.3K
Colloids and Suspensions01:17

Colloids and Suspensions

1.7K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
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Distillation: Vapor–Liquid Equilibria01:01

Distillation: Vapor–Liquid Equilibria

2.7K
Distillation is a separation technique that takes advantage of the boiling point properties of disparate elements in a mixture. To perform distillation, we begin by heating a miscible mixture of two liquids with a significant difference in boiling points (at least 20°C). As the solution heats up and reaches the bubble point of the more volatile component, some molecules of the more volatile component transition into the gas phase and travel upward into the condenser, which is a glass tube...
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Methods for the Self-integration of Megamolecular Biopolymers on the Drying Air-LC Interface
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在干燥二元合膜中进行自我分层和相分离.

Ellard Hooiveld1, Lisa Rijnders1, Berend van der Meer1

  • 1Physical Chemistry and Soft Matter, Wageningen University & Research, Stippeneng 4, Wageningen, 6708 WE, the Netherlands.

Journal of colloid and interface science
|October 25, 2024
PubMed
概括

研究人员在干燥过程中在合膜中实现了自我分层和微相分离. 这种同时的大小分离提供了一个新的策略,用于创建可定制的功能性涂层,具有量身定制的特性.

关键词:
二元合膜是二元的合膜.这是一种扩散性化.分散干燥是分散干燥的方法.在现场共聚焦成像成像多元件涂层是多元件的涂层.非平衡的热力学.阶段分离 阶段分离 阶段分离分层分层是指分层的分层.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 体科学 体科学 体科学
  • 软物质物理学 软物质物理学

背景情况:

  • 干燥的合膜可以为量身定制的功能开发组成的异质性.
  • 体颗粒的自发大小分离,包括自我分层和微域形成,是已知的机制.
  • 这些分离现象在蒸发过程中的二元合膜中并未同时研究.

研究的目的:

  • 研究干燥过程中二元合膜中同时发生的自我分层和微域形成的情况.
  • 了解各种参数对构成异质性出现的影响.

主要方法:

  • 使用实时3D共聚焦光显微镜.
  • 量化分析了粒子大小比率,初始体积分数,蒸发率和盐度的影响.

主要成果:

  • 在关键粒子大小比率之外,微相分离成为主导.
  • 最初的体积分数显著影响自我分层,但不影响域大小.
  • 降低蒸发速度会增加域大小,降低分层.
  • 减少的体静电相互作用增强相位分离,但反转了分层.

结论:

  • 展示了一种单步方法,在干燥二元合膜时实现自我分层和微域形成.
  • 确定了控制这些隔离机制的关键参数.
  • 为开发具有可调节功能的可定制自分区涂层奠定了基础.